1983
DOI: 10.1016/0022-4596(83)90029-4
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Preparation and properties of substituted iron tungstates

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1985
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Cited by 15 publications
(13 citation statements)
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“…The material is composed of "zig-zag" chains of edge-sharing oxygen octahedra with one-third of the chains containing only iron whilst the remainder comprise alternating W-and Fe-centred octahedra (4,7,8). Hence it is possible that there might be slight differences between the electric field gradients at the iron nuclei in the two types of chains.…”
Section: Iron-tungsten Oxidesmentioning
confidence: 99%
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“…The material is composed of "zig-zag" chains of edge-sharing oxygen octahedra with one-third of the chains containing only iron whilst the remainder comprise alternating W-and Fe-centred octahedra (4,7,8). Hence it is possible that there might be slight differences between the electric field gradients at the iron nuclei in the two types of chains.…”
Section: Iron-tungsten Oxidesmentioning
confidence: 99%
“…However, Leiva et al (7,8) suggest the presence of a partially reduced iron species with delocalization of the d6 electron of the Fe(I1) over all iron atoms. If hopping due to this delocalization is slow on the Moessbauer time scale, then a separate Fe2+ doublet should be observed.…”
Section: Iron-tungsten Oxidesmentioning
confidence: 99%
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