Preparation and protonation reactions of aryl complexes of manganese and rhenium

Albertin, Gabriele; Antoniutti, Stefano; Castro, Jesús; Carniato, Stefano; García‐Fontán, Soledad

doi:10.1016/j.jorganchem.2006.09.005

Cited by 6 publications

References 32 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Synthesis and Characterization of Di‐ and Tricarbonylhydridomanganese(I) Complexes

Bolaño

Bravo

Castro

et al. 2009

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

Hydrido complexes [MnH(CO)3L1–3] [L1 = 1,2‐bis‐(diphenylphosphanoxy)‐ethane (1); L2 = 1,2‐bis‐(diisopropylphosphanoxy)ethane (2); L3 = 1,3‐bis‐(diphenylphosphanoxy)‐propane (3)] were prepared by treating [MnH(CO)5] with the appropriate bidentate ligand by heating to reflux. Photoirradiation of a toluene solution of complexes 1 and 2 in the presence of PPhn(OR)3–n (n = 0, 1; R = Me, Et) leads to the replacement of a CO ligand by the corresponding monodentate phosphite or phosphonite ligand to give new hydrido compounds of formula [MnH(CO)2(L1–2)(L)] [L = P(OMe)3 (1a–2a); P(OEt)3 (1b–2b); PPh(OMe)2 (1c–2c); PPh(OEt)2 (1d–2d)]. All complexes were characterized by IR, 1H, 13C and 31P NMR spectroscopy. In case of compounds 2 and 3, suitable crystals for X‐ray diffraction studies were isolated.

show abstract

Synthesis and Characterization of Di‐ and Tricarbonylhydridomanganese(I) Complexes

Bolaño

Bravo

Castro

et al. 2009

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

Synthesis and Characterization of New Chlorocarbonylrhenium(I) Complexes with P‐Donor Chelate Ligands

Bolaño

Bravo

Castro

et al. 2010

Zeitschrift anorg allge chemie

Self Cite

View full text Add to dashboard Cite

Chlorocarbonylrhenium(I) complexes fac,cis‐[ReCl(CO)3L1–3][L1 = Ph2PO(CH2)2OPPh2 (1); L2 = Ph2PO(CH2)3OPPh2 (2); L3 = iPr2PO(CH2)2OPiPr2 (3)] were synthesized by reaction of [ReCl(CO)5] with the appropriate diphosphinite ligands L1–3. Reaction of mer,cis‐[ReH(CO)3L2] with HCl affords an isomer of compound 2, the complex mer,cis‐[ReCl(CO)3L2] (4). The new complexes were characterized by IR, 1H, 13C{1H} and 31P{1H} NMR spectroscopy and in the case of complexes 2 and 4 by single‐crystal X‐ray structure determination.

show abstract

Metal-Carbon Bonds of Heavier Group 7 and 8 Metals (Tc, Re, Ru, Os): Mononuclear Tc/Re/Ru/Os Complexes With Metal-Carbon Bonds

Wei

Jia

2021

Comprehensive Coordination Chemistry III

View full text Add to dashboard Cite

Preparation and protonation reactions of aryl complexes of manganese and rhenium

Cited by 6 publications

References 32 publications

Synthesis and Characterization of Di‐ and Tricarbonylhydridomanganese(I) Complexes

Synthesis and Characterization of Di‐ and Tricarbonylhydridomanganese(I) Complexes

Synthesis and Characterization of New Chlorocarbonylrhenium(I) Complexes with P‐Donor Chelate Ligands

Metal-Carbon Bonds of Heavier Group 7 and 8 Metals (Tc, Re, Ru, Os): Mononuclear Tc/Re/Ru/Os Complexes With Metal-Carbon Bonds

Contact Info

Product

Resources

About