2019
DOI: 10.1002/zaac.201900037
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Preparation and Reactivity of Mixed‐Ligands Hydride Complexes [RuHCl(CO)(PPh3)2{P(OR)3}]

Abstract: Mixed-ligands hydride complexes [RuHCl(CO)(PPh 3 ) 2 {P(OR) 3 }] (2) (R = Me, Et) were prepared by allowing [RuHCl(CO)(PPh 3 ) 3 ] (1) to react with an excess of phosphites P(OR) 3 in refluxing benzene. Treatment of hydrides 2 first with triflic acid and next with an excess of hydrazine afforded hydrazine complexes [RuCl(CO)(κ 1 -NH 2 NHR1)(PPh 3 ) 2 {P(OR) 3 }]BPh 4 688(3, 4) (R1 = H, CH 3 ). Diethylcyanamide derivatives [RuCl(CO)(NϵCNEt 2 )(PPh 3 ) 2 {P(OR) 3 }]BPh 4 (5) were also prepared by reacting 2 firs… Show more

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