Preparation and Sensitivity Measurements of Graphene Oxide-RDX Composite

Abstract

Abstract. The effect of graphene oxide (GO) on the safety characteristics of 1,3,5-trinitro-1,3,5-triazinane (RDX) was studied in this work. Graphene oxide was prepared and was investigated to form a composite based on GO-RDX by solvent-antisolvent slurry technique. For comparison, different polymer bonded explosives (PBXs) based on RDX bonded by viton A, fluorel or polymethyl-methacrylate binders were studied and designed as RDX-Viton, RDX-Fluorel and RDX-PMMA respectively. Sensitivities to impact and friction of the presented samples as well as the pure RDX was measured. The ignition temperatures were determined and the activation energies were calculated by using the ignition delay method. Results of x-ray diffraction and scanning electron microscope proved that RDX crystals were coated by a thin layer of GO. The impact sensitivity of GO-RDX composite is lower than that of the other studied samples while the friction sensitivity is slightly higher. The ignition temperature of GO-RDX was lower than the other studied samples which indicates that the GO caused accumulation of the decomposition gaseous products and accelerated the decomposition process of RDX. GO is an interesting candidate material to be used for coating the explosive crystals instead of the polymeric matrices.

Atomistic insight into enhanced thermal decomposition of energetic material on graphene oxide

“…In the presence of GO, E a is reduced by 11.35% compared with pure RDX, demonstrating that GO promotes RDX reactions. E a of pure RDX decomposition reported from experiments varies from 103 to 272 kJ/mol as summarized in a previous study [31] , and the experimentally derived E a of RDX/GO is 122 [7] and 131 kJ/mol [36] . The discrepancy in E a between the present research and experiments is generally acceptable as a result of the various different conditions adopted including temperature, particle size, structure and loading of GO, calculation methods as well as uncertainties and errors in both the computational and experimental studies.…”

Preparation, Characterization and Application of Nano-Graphene-Based Energetic Materials

“…This is because graphene consumes some of its total energy to burn itself during the explosion. Zorainy et al [29] prepared the graphene-RDX composite using the solvent/anti-solvent method. Compared with three kinds of Polymer-bonded explosives based on RDX (PBXs), the impact sensitivity of the graphene-RDX composite containing 2 wt% graphenes was lower than that of the PBXs containing 9 wt% RDX.…”