2019
DOI: 10.4283/jmag.2019.24.1.049
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Preparation and Stability Study of Carboxyl Terminated Silicone Oil Modified Silicone-oil-based Ferrofluid

Abstract: In this study, ferrofluids were prepared by colloidal dispersion of paramagnetic Fe 3 O 4 nanoparticles coated with long-chain carboxyl terminated silicone oil in silicone oil. Effect of pH value of the aqueous solution on coating was investigated. The IR and TG analysis indicated that acid conditions favored the coating of carboxyl terminated silicone oil. Stabilities of ferrofluids were characterized by density change and mass specific saturated magnetization change during centrifugation and static settlemen… Show more

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Cited by 7 publications
(1 citation statement)
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“…Magnetic separation methods were developed to narrow the particle size distribution of the magnetite nanoparticles using tricarboxylate PDMS stabilizer while controlling the PDMS surface concentration [ 161 ]. In other studies, a monocarboxydecyl-terminated PDMS macromer (MCR-B12) was used to stabilize magnetite nanoparticles; however, the resulting ferrofluids had issues with stability and sedimentation, likely due to the lower number of carboxylate binding groups per macromer chain [ 88 ]. The magnetophoretic mobility of the magnetite-PDMS fluids was then studied in different magnetic field conditions (magnetic fields and field gradients), with the results demonstrating that the shape and speed of these droplets in viscous media can be independently manipulated [ 160 , 162 ].…”
Section: Applicationsmentioning
confidence: 99%
“…Magnetic separation methods were developed to narrow the particle size distribution of the magnetite nanoparticles using tricarboxylate PDMS stabilizer while controlling the PDMS surface concentration [ 161 ]. In other studies, a monocarboxydecyl-terminated PDMS macromer (MCR-B12) was used to stabilize magnetite nanoparticles; however, the resulting ferrofluids had issues with stability and sedimentation, likely due to the lower number of carboxylate binding groups per macromer chain [ 88 ]. The magnetophoretic mobility of the magnetite-PDMS fluids was then studied in different magnetic field conditions (magnetic fields and field gradients), with the results demonstrating that the shape and speed of these droplets in viscous media can be independently manipulated [ 160 , 162 ].…”
Section: Applicationsmentioning
confidence: 99%