Preparation and structural study of a novel nonlinear molecular material: the l-histidinum dihydrogenarsenate orthoarsenic acid crystal

Ratajczak, H.; Barycki, J.; Pietraszko, A.; Baran, J.; Debrus, S.; May, M.; Venturini, J.

doi:10.1016/s0022-2860(00)00534-2

Cited by 58 publications

(35 citation statements)

References 7 publications

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“…The above assignment is similar to L-histidinium tetrafluorosuccinate crystal [15]. Ratajczak et al [12], wrote that the lack of any strong IR band at 1700 cm -1 clearly indicates that L-histidine possess COO -ion and exists in zwitterionic form. Similar vibration for COO -group are also observed in Raman giving weak absorptions at 1531 and 1434 cm -1 .…”

Section: Vibrations Of Carboxylate Groupmentioning

confidence: 62%

Crystal structure and vibrational analysis of novel nonlinear optical L‐histidinium tetrafluoroborate (L‐HFB) single crystals

Raj

Kumar

Mohan

et al. 2007

Physica Status Solidi (b)

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Single crystals of L-histidinium tetrafluoroborate (L-HFB) were grown by slow evaporation of an aqueous solution at room temperature. The crystal structure has been elucidated through single crystal X-ray crystallography. The infrared (IR) and Raman spectroscopic measurements fully confirm the X-ray crystal structure. The potential role of hydrogen bonds of the title crystal and its influence on interaction between the L-histidinium cation and tetrafluoroborate anion has been discussed in detail. The crystal is a very good second harmonic generator. Its powder SHG efficiency is calculated as d eff = 1.70 d eff (KDP).

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Section: Vibrations Of Carboxylate Groupmentioning

confidence: 62%

Crystal structure and vibrational analysis of novel nonlinear optical L‐histidinium tetrafluoroborate (L‐HFB) single crystals

Raj

Kumar

Mohan

et al. 2007

Physica Status Solidi (b)

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“…[ 21 , 30 ] In principle, generating bio-analogous MOFs may be realized by using bioactive organic ligands such as amino acids, hydroxyl carboxylic acids, nucleotide acids, cinchona alkaloids, peptides and biotin. [36][37][38][39][40] These bioactive species are the origin for the functional properties and highly selective substrate-binding ability of many extended biological structures, and so are attractive options as chiral building blocks for such purposes. Another option is the combination of fl exible organic linkers with rich hydrophobic and/or hydrophilic groups with coordination bonds.…”

Section: Reviewmentioning

confidence: 99%

Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

2010

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Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal-organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation.

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“…The structural and SHG studies of L-histidinum dihydrogenarsenate orthoarsenic acid (LHA) was reported by Ratajczak et al [10]. LHP is one such efficient nonlinear material which is isostructural to LHA [10]. In the present investigation, bulk crystals of LHP were grown and reported for the first time.…”

Section: Introductionmentioning

confidence: 61%

“…However, salts of L-histidine received wide attention with the discovery of the promising properties of L-His.HBF 4 [9]. The structural and SHG studies of L-histidinum dihydrogenarsenate orthoarsenic acid (LHA) was reported by Ratajczak et al [10]. LHP is one such efficient nonlinear material which is isostructural to LHA [10].…”

Section: Introductionmentioning

confidence: 98%

Crystallization and characterization of nonlinear optical l‐histidinium dihydrogen orthophosphate orthophosporic acid single crystal

Madhavan¹,

Aruna²,

Ambujam³

et al. 2006

Cryst. Res. Technol.

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acid (abbreviated as LHP) with molecular formula.H 3 PO 4 was successfully grown by slow evaporation technique from aqueous solution. The crystal was characterized by X-ray diffractometry (XRD), UV-Vis-NIR, TGA, DTA, microhardness and solubility studies. The dielectric constant and dielectric loss of the crystal were studied as function of frequency. Photoconductivity studies were also carried out on the sample. The SHG efficiency of the crystal is studied using the Kurtz and Perry technique.

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Preparation and structural study of a novel nonlinear molecular material: the l-histidinum dihydrogenarsenate orthoarsenic acid crystal

Cited by 58 publications

References 7 publications

Crystal structure and vibrational analysis of novel nonlinear optical L‐histidinium tetrafluoroborate (L‐HFB) single crystals

Crystal structure and vibrational analysis of novel nonlinear optical L‐histidinium tetrafluoroborate (L‐HFB) single crystals

Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

Crystallization and characterization of nonlinear optical l‐histidinium dihydrogen orthophosphate orthophosporic acid single crystal

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