Preparation and thermal properties of Alkoxy Silane functionalized polyether sulfone/well‐defined poly(trimethoxysilyl) propyl methacrylate‐based hybrid materials

Oktay, Burcu; Baştürk, Emre; Kahraman, Memet Vezi̇r; Kayaman‐Apohan, Nilhan

doi:10.1002/pen.24714

Cited by 2 publications

(1 citation statement)

References 29 publications

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“…Sol–gel techniques have been widely used for the preparation of organic–inorganic hybrid materials. The inorganic network is obtained from metal‐alkoxysilanes via hydrolysis and condensation reactions .…”

Section: Introductionmentioning

confidence: 99%

UV‐curable sol–gel based protective hybrid coatings

İnan

Seden

Baştürk

et al. 2018

Polymer Engineering & Sci

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UV‐curable, novel, fluorinated polyether ether ketone urethane acrylate oligomer (FPEEKUA) has been synthesized and used as corrosion‐protector in sol–gel hybrid coatings for metallic substrates. Incorporation of FPEEKUA and sol–gel in the formulations improved coatings’ physical properties such as gel content, hardness, adhesion, gloss, flexibility, and contact angle. Due to strong interaction between acrylate and highly crosslinked structures, mechanical properties improved drastically with homogenously dispersed structures throughout the organic matrix, while water uptake values decreased and thermal stability and char yields increased. Highest contact angle values were measured up to 94° with shinny coatings. The results are important for two reasons. First, polyether ether ketone (PEEK) immiscibility problem are overcome by using reactive oligomer and benefitted from high performance properties of poly(arylene ether ketones) (PAEK)s in hybride coating applications. Second, Coatings combine the advantages of sol–gel with poly(arylene ether ketone urethane acrylate) (PAEKUA) oligomer and they can be used as barrier coatings in metal corrosion protection. Performance tests in corrosive mediums at room temperature of chlorine solution (bleach) for 24 h and also in a 10 wt% HCl solution for 92 h produced promising results for use in corrosion mitigation applications in highly corrosive downstream oil and gas industry. POLYM. ENG. SCI., 59:E146–E154, 2019. © 2018 Society of Plastics Engineers

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Section: Introductionmentioning

confidence: 99%

UV‐curable sol–gel based protective hybrid coatings

İnan

Seden

Baştürk

et al. 2018

Polymer Engineering & Sci

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A strategy for synthesis of silane terminated polyether triggered by click reaction and its application in preparation of modified silane sealants

Li,

Guo,

et al. 2023

AIP Advances

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A new hydroxy-silane coupling agent was synthesized from 3-butene-1-alcohol and mercaptopropyl-3-methoxysilane based on a click reaction between double bonds and sulfhydryl groups and was successfully used in the synthesis of silane-modified polyether (STPE). The effect of molecular weight of polypropylene glycol (PPG) on the properties of silane-modified polyether was studied. It was found that with the increase in PPG molecular weight, the initial thermal decomposition temperature and hardness of STPE elastomers decreased, but the molecular structure hardly changed. In addition, with the increase in molecular weight, the elongation at break of the elastomer will gradually increase, but the tensile strength of the elastomer does not change much. When the molecular weight reaches 20 000 g/mol, the resin with a viscosity of 1.6 × 105 mPa s can be obtained, and the elongation at break of the cured elastomer reaches 383.4% and the tensile strength is 0.25 MPa. After the STPE resin was prepared into a silane modified sealant, the tensile strength reached 1.31 MPa and the elongation at break reached 406.2%, which had the best mechanical properties among the prepared sealants. This shows that the sealant prepared from high molecular weight resin has stronger mechanical properties, which provides a new idea for the preparation of sealants.

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Preparation and thermal properties of Alkoxy Silane functionalized polyether sulfone/well‐defined poly(trimethoxysilyl) propyl methacrylate‐based hybrid materials

Cited by 2 publications

References 29 publications

UV‐curable sol–gel based protective hybrid coatings

UV‐curable sol–gel based protective hybrid coatings

A strategy for synthesis of silane terminated polyether triggered by click reaction and its application in preparation of modified silane sealants

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