Preparation, Characterization and Evaluation of Polyamide-Reduced Graphene Oxide as Selective Membranes for Water Purification

Abstract

Amidst the ongoing advancements in membrane technology, a leading method has come to the forefront. Recent research has emphasized the substantial influence of surface attributes in augmenting the effectiveness of thin-film membranes in water treatments. These studies reveal how surface properties play a crucial role in optimizing the performance of these membranes, further establishing their prominence in the field of membrane technology. This recognition stems from the precise engineering of surfaces, ensuring they meet the demanding requirements of advanced separation processes. This study utilizes polyamide as a discerning layer, applied atop a polysulfone support sheet through interfacial polymerization (IP) for membrane fabrication. The amounts in the various membranes were created to vary. The membrane’s permeability to water with significant salt rejection was enhanced, which improved its effectiveness. The polyamide (PA) membrane comprising graphene oxide (rGO, 0.015%) had a water permeability of 48.90 L/m2 h at 22 bar, which was much higher than the mean permeability of polyamide membranes (25.0 L/m2 h at 22 bar). On the other hand, the PA–rGO/CHIT membranes exhibited the lowest water permeability due to their decreased surface roughness. However, the membranes’ effectiveness in rejecting salts ranged from 80% to 95% for PA–rGO and PA–rGO/CHIT membranes.

Footsteps of graphene filled polymer nanocomposites towards efficient membranes—Present and future

“…Moreover, the nanofiltration membranes have a high adsorption rate of 79.8%, relative to neat polymer membranes (26.7%). Alshahrani et al [95] used the interfacial polymerization method for polysulfone/reduced graphene oxide membrane fabrication. Including 0.015% nanofiller in polyamide led to a water permeability of 48.9 L/m 2 h, higher than the neat polyamide membrane (25.0 L/m 2 h).…”