Preparation, characterization and reactivity of trifluoromethoxy palladium(ii) complexes

Abstract

The preparation of the first nitrogen- or phosphine-ligated trifluoromethoxylated Pd(II) complexes [(L)Pd(4-CF3Ph)(OCF3)] (L = TMEDA, 4-Mepyridine or tBu-BrettPhos, BrettPhos, RuPhos and CPhos) was described. These complexes were extensively characterized in...

[(tBu2PhP)Ag(μ-OCF3)]2: A Thermally Stable, Light-Insensitive Nucleophilic Reagent for Trifluoromethoxylation

“…Despite these intriguing properties, methods for the direct introduction of the CF 3 O group remain underdeveloped. In this respect, in the past ten years, a few nucleophilic trifluoromethoxylating reagents − as well as trifluoromethoxy radical precursors have been reported, significantly expanding the arsenal of the trifluoromethoxylating methodologies. , …”