Preparation of 1-silyl- and 1,3-disilyl-adamantanes

Pai, Yi-Ming; Wanek, Erich; Weber, William P.

doi:10.1016/0022-328x(84)80373-3

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-Haloadamantanes and Dihaloadamantanes1

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1985

2024

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Cited by 13 publications

(1 citation statement)

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“…1,3-Dibromoadamantane and 1-ClAd react with LiSiPhMe 2 to give 95 and 93% of the di-and monosubstitution products, respectively. 390 No mechanistic information is given for the reaction.…”

Section: -Haloadamantanes and Dihaloadamantanesmentioning

confidence: 99%

Nucleophilic Substitution Reactions by Electron Transfer

2002

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“…1,3-Dibromoadamantane and 1-ClAd react with LiSiPhMe 2 to give 95 and 93% of the di-and monosubstitution products, respectively. 390 No mechanistic information is given for the reaction.…”

Section: -Haloadamantanes and Dihaloadamantanesmentioning

confidence: 99%

Nucleophilic Substitution Reactions by Electron Transfer

2002

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By Reaction with Organic Halides to Eliminate MX

Cartledge¹,

Piccione²

1991

Inorganic Reactions and Methods

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Application of Solid Me₃SiZnI for the Synthesis of Aryl and Alkyl Trimethylsilanes

Ganguly,

Chandrasekaran,

Balamurugan

et al. 2024

Adv Synth Catal

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Transition metal catalysis employing disilanes and silylboranes for synthesizing organosilanes circumvents the limitations of conventional hydrosilylations. While disilanes require special conditions, silylboranes have yet to be developed as TMS sources. Functional group compatibility renders silylzinc reagents desirable; however, their development is hindered by their synthesis using pyrophoric silyllithium and dissolved lithium salts. Our solid Me3SiZnI circumvents these limitations and herein, we demonstrate its significance in the cross‐coupling of aryl and alkyl bromides.

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Preparation of 1-silyl- and 1,3-disilyl-adamantanes

Cited by 13 publications

References 13 publications

Nucleophilic Substitution Reactions by Electron Transfer

Nucleophilic Substitution Reactions by Electron Transfer

By Reaction with Organic Halides to Eliminate MX

Application of Solid Me₃SiZnI for the Synthesis of Aryl and Alkyl Trimethylsilanes

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Preparation of 1-silyl- and 1,3-disilyl-adamantanes

Cited by 13 publications

References 13 publications

Nucleophilic Substitution Reactions by Electron Transfer

Nucleophilic Substitution Reactions by Electron Transfer

By Reaction with Organic Halides to Eliminate MX

Application of Solid Me3SiZnI for the Synthesis of Aryl and Alkyl Trimethylsilanes

Contact Info

Product

Resources

About

Application of Solid Me₃SiZnI for the Synthesis of Aryl and Alkyl Trimethylsilanes