Preparation of a novel Ni-MOF and porous graphene aerogel composite and application for simultaneous electrochemical determination of nitrochlorobenzene isomers with partial least squares

Niu, Xiaohui; Lin, Jianyan; Bai, Jing; Guo, Liping

doi:10.1007/s00604-020-04371-y

Cited by 8 publications

(2 citation statements)

References 34 publications

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“…28 Niu et al prepared metal-organic framework Ni 2 (BDC) 2 (DABCO) (Ni-MOF)/porous graphene aerogel (PGA) for application in simultaneous electrochemical determination of nitrochlorobenzene isomers with partial least squares. 29 Nevertheless, to our knowledge, few reports explore the preparation of PA-CoMn organic gel for drug sensing.…”

Section: Introductionmentioning

confidence: 99%

A phytic acid-based CoMn bimetallic metal–organic aerogel (PA–CoMn-1 : x : 2 − x) as a modifier for electrochemical detection of non-steroidal anti-inflammatory drug 4-acetaminophenol

Guo,

Qi,

Wang

et al. 2024

RSC Adv.

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Section: Introductionmentioning

confidence: 99%

A phytic acid-based CoMn bimetallic metal–organic aerogel (PA–CoMn-1 : x : 2 − x) as a modifier for electrochemical detection of non-steroidal anti-inflammatory drug 4-acetaminophenol

Guo,

Qi,

Wang

et al. 2024

RSC Adv.

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“…17 The electrochemical properties of aromatic nitro compounds vary greatly with the type of substituents and their position on the benzene ring. Generally, the reduction potential of aromatic nitro compounds with an electron-withdrawing substituent is more positive, 18 while that of aromatic nitro compounds with an electron-donating substituent is more negative owing to the increased electron cloud density of the nitro group. However, how do electrondonating groups affect the electrochemical degradation of aromatic nitro compounds in aprotic media containing CO 2 has been rarely studied.…”

Section: ■ Introductionmentioning

confidence: 99%

Effect of Electron-Donating Groups on the Electrochemical Degradation of Aromatic Nitro Compounds in Aprotic Media Containing CO₂

Meng

Wang

et al. 2021

J. Phys. Chem. C

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The electrochemical degradation of p-nitrochlorobenzene in aprotic media containing CO2 is reported. Little is known about the effects of electron-donating groups on electrochemical degradation of aromatic nitro compounds. Accordingly, electrochemical behavior of nitrobenzene (NB), para-nitrotoluene (PNT), and para-nitroanisole (PNA), in an aprotic solvent containing CO2, was investigated by cyclic voltammetry (CV), in situ Fourier transform infrared (FT-IR) spectroscopy, and potenstiostatic electrolysis. It was established that their electrochemical reduction was an irreversible four-electron transfer process. Based on cyclic voltabsorptometry (CVA), derivative cyclic voltabsorptometry (DCVA), and chronoamperometry (CA), a mechanism of electroreduction of aromatic nitro compounds in the presence of CO2 was proposed. The products of potenstiostatic electrolysis, in the presence of CO2, were characterized by X-ray single-crystal diffraction, 13C NMR, and 1H NMR. NB and PNT gave only the corresponding azo compound with a 99% conversion rate. However, the conversion rate of PNA was lower (78%) due to the effect of the strong electron-donating methoxy group. The intermediate reduction product 4,4′-dimethoxyazoxybenzene was formed along 4,4′-dimethoxyazobenzene. In the process, CO2 was converted to CO3 2–. This constitutes a new way of carbon sequestration.

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Strongly coupled design of zinc oxide-nanorods/copper tin sulfide-nanoflowers nanostructures: An electrochemical study in 4-nitrochlorobenzene detection

Kokulnathan,

Vishnuraj,

Wang

et al. 2024

Chemical Engineering Journal

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Preparation of a novel Ni-MOF and porous graphene aerogel composite and application for simultaneous electrochemical determination of nitrochlorobenzene isomers with partial least squares

Cited by 8 publications

References 34 publications

A phytic acid-based CoMn bimetallic metal–organic aerogel (PA–CoMn-1 : x : 2 − x) as a modifier for electrochemical detection of non-steroidal anti-inflammatory drug 4-acetaminophenol

A phytic acid-based CoMn bimetallic metal–organic aerogel (PA–CoMn-1 : x : 2 − x) as a modifier for electrochemical detection of non-steroidal anti-inflammatory drug 4-acetaminophenol

Effect of Electron-Donating Groups on the Electrochemical Degradation of Aromatic Nitro Compounds in Aprotic Media Containing CO₂

Strongly coupled design of zinc oxide-nanorods/copper tin sulfide-nanoflowers nanostructures: An electrochemical study in 4-nitrochlorobenzene detection

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Preparation of a novel Ni-MOF and porous graphene aerogel composite and application for simultaneous electrochemical determination of nitrochlorobenzene isomers with partial least squares

Cited by 8 publications

References 34 publications

A phytic acid-based CoMn bimetallic metal–organic aerogel (PA–CoMn-1 : x : 2 − x) as a modifier for electrochemical detection of non-steroidal anti-inflammatory drug 4-acetaminophenol

A phytic acid-based CoMn bimetallic metal–organic aerogel (PA–CoMn-1 : x : 2 − x) as a modifier for electrochemical detection of non-steroidal anti-inflammatory drug 4-acetaminophenol

Effect of Electron-Donating Groups on the Electrochemical Degradation of Aromatic Nitro Compounds in Aprotic Media Containing CO2

Strongly coupled design of zinc oxide-nanorods/copper tin sulfide-nanoflowers nanostructures: An electrochemical study in 4-nitrochlorobenzene detection

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Effect of Electron-Donating Groups on the Electrochemical Degradation of Aromatic Nitro Compounds in Aprotic Media Containing CO₂