Preparation of a novel supramolecular intumescent flame retardants containing P/N/S/Fe/Zn and its application in polylactic acid

Liu, Qinyong; Chen, Xingyu; Zhu, Gui-Yang; Gu, Xiaoyu; Li, Hongfei; Sun, Jun; Jin, Xiaodong

doi:10.1016/j.firesaf.2022.103536

Cited by 19 publications

(14 citation statements)

References 49 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It can be analyzed from the fine spectrogram of Figure 2e, in which two peaks of 712.2 and 726.1 eV belong to Fe 2p 2/3 and Fe 2p 1/2 . 27 The O 1s region can be fitted to three peaks corresponding to P−O−P, P�O, and O−Fe bonds, which proves that Fe ions are complexed with phenolic hydroxyl groups in TA.…”

Section: ■ Materials and Methodsmentioning

confidence: 82%

Toward Flame Retardancy, Antimelt Dripping, and UV Resistance Properties of Polylactic Acid Based on Eco-Friendly Core–Shell Flame Retardant

Ma,

Jiang,

Liu

et al. 2024

ACS Appl. Polym. Mater.

View full text Add to dashboard Cite

To enhance the flame retardancy of polylactic acid (PLA), the exploration of bioderived flame retardants has captured the focus of researchers globally. Herein, a core−shell bioderived flame retardant is prepared through electrostatic self-assembly using ammonium polyphosphate (APP) as the core and chitosan (CS)/ tannic acid (TA) bilayer as the shell. In addition, the Fe 3+ ion is introduced into the outermost TA shell through coordination with the phenolic hydroxyl group, which can reduce the droplets during combustion.

show abstract

Section: ■ Materials and Methodsmentioning

confidence: 82%

Toward Flame Retardancy, Antimelt Dripping, and UV Resistance Properties of Polylactic Acid Based on Eco-Friendly Core–Shell Flame Retardant

Ma,

Jiang,

Liu

et al. 2024

ACS Appl. Polym. Mater.

View full text Add to dashboard Cite

show abstract

“…However, the flammability of PLA is not good and accompanied by severe dripping, which limits its application in electronic appliances, automobiles, and other fields that require strict fire-resistant performance. 11,12 Therefore, improving the flameretardant properties of PLA has become an inevitable choice.…”

Section: Introductionmentioning

confidence: 99%

“…It has been widely used in medicine, packaging, 3D printing and agriculture due to its attractive properties, such as biocompatibility, high strength, and transparency. However, the flammability of PLA is not good and accompanied by severe dripping, which limits its application in electronic appliances, automobiles, and other fields that require strict fire‐resistant performance 11,12 . Therefore, improving the flame‐retardant properties of PLA has become an inevitable choice.…”

Section: Introductionmentioning

confidence: 99%

An overview of the recent advances in flame retarded poly(lactic acid)

Baochai

Bakar

Mohamad

2023

Polymers for Advanced Techs

View full text Add to dashboard Cite

Poly(lactic acid) (PLA) is derived from crops, and has a broad application prospect in electronics and electrical, automotive industries due to its biodegradability and good physical and mechanical properties. However, PLA's flammability and serious melt dripping cannot meet the requirements of terminal products, thus limiting its application. Over the past decade, much research on flame retardant PLA has emerged. This paper reviews the development of PLA flame retardants in recent years, focusing on phosphorus-based, phosphorus-nitrogen-based, bio-based, nanoparticles, intumescent flame retardants, and their combinations. Besides that, the efficiency of flame retardant and its loading on the thermal and mechanical properties of PLA is also thoroughly reviewed. Finally, the future development of flame-retardant PLA is briefly summarized and prospected.

show abstract

“…The demand for PLA is now shifting to more durable materials to replace petroleum‐based thermoplastics in construction, automotive, and electronic devices. In these areas, there are strict requirements for fire resistance, but PLA has poor flame retardancy, and the poor flame retardant properties of PLA need to be improved 10,11 …”

Section: Introductionmentioning

confidence: 99%

“…In these areas, there are strict requirements for fire resistance, but PLA has poor flame retardancy, and the poor flame retardant properties of PLA need to be improved. 10,11 Flame retardancy methods include chemical modifications and physical additives. Chemical modifications are more complicated, modifying the structure of PLA to achieve inherent flame retardancy, which is difficult to commercialize.…”

Section: Introductionmentioning

confidence: 99%

Effects of ammonium polyphosphate and casein on the properties of poly (lactic acid)

et al. 2023

View full text Add to dashboard Cite

In this paper, ammonium polyphosphate (APP) and casein (CSN) were added to poly (lactic acid) (PLA) to improve flame retardancy and maintain biodegradability. The flame retardancy, mechanical, and thermal properties of PLA/APP/CSN composites were evaluated, and the optimum ratio of APP and CSN was determined. The results showed that with the addition of 9 wt% flame retardant (APP:CSN=5:4), the limiting oxygen index (LOI) of the PLA/APP/CSN composite reached 28.3%, and passed the UL‐94 V‐0 rating at 3 mm, char residue increased at 800°C and smoke emission was also significantly reduced compared to addition of APP without the addition of CSN. Besides that, the cone calorimeter result showed that the peak heat release rate and total heat release of the PLA/APP/CSN‐5 composite were 18.2% and 13.3%, respectively, lower than those of pure PLA. The addition of flame retardants inevitably led to a reduction in tensile and flex strength values, but the impact strength was improved.

show abstract

Preparation of a novel supramolecular intumescent flame retardants containing P/N/S/Fe/Zn and its application in polylactic acid

Cited by 19 publications

References 49 publications

Toward Flame Retardancy, Antimelt Dripping, and UV Resistance Properties of Polylactic Acid Based on Eco-Friendly Core–Shell Flame Retardant

Toward Flame Retardancy, Antimelt Dripping, and UV Resistance Properties of Polylactic Acid Based on Eco-Friendly Core–Shell Flame Retardant

An overview of the recent advances in flame retarded poly(lactic acid)

Effects of ammonium polyphosphate and casein on the properties of poly (lactic acid)

Contact Info

Product

Resources

About