Preparation of Amino-functionalized Guanidinium Ionic Liquid-Modified Magnetic Materials and Application in Solid-Phase Extraction of Pollutants in Water

Qiao, Lizhen; Yu, Chunmei; Sun, Ruiting

doi:10.1007/s41664-021-00188-7

Cited by 14 publications

(4 citation statements)

References 36 publications

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“…Some examples are carbon-based materials, metal and metal oxides, silica-based materials, porous polymers, metal-organic frameworks, ionic liquids, molecularly imprinted polymers, and bio-sorbents. [14,15] Metal organic framework TMU-6 modified iron nanoparticles, [16] magnetic molecularly imprinted polymers, [17] magnetic carbon-doped CoO nanocomposite, [2] amino-functionalized guanidinium ionic liquid-modified magnetic materials, [18] phenyl-modified magnetic silica [19] are some of magnetic sorbents used for the extraction of PAHs.…”

Section: Introductionmentioning

confidence: 99%

Magnetic Polyeugenol Nanoparticles as a New Sorbent for Solid‐Phase Extraction of Polycyclic Aromatic Hydrocarbons in Environmental Water and Food Samples

2023

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In this study, the magnetized polyeugenol was applied as an efficient adsorbent for pre‐concentration of five target polycyclic aromatic hydrocarbons (PAHs), acenaphthene, fullerene, phenanthrene, fluoranthene and pyrene, in the aqueous samples. Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, transmission electron microscopy, thermo‐gravimetric and zeta‐potential analyses, and vibration sample magnetometry were utilized for characterization of the prepared nanocomposite. Key parameters in the extraction efficiency of PAHs including pH, salt content, adsorbent amount, extraction time and volume of desorption solvent were optimized. Under the optimal conditions, a linear response was observed in the concentration range of 1–75 μg L−1 (R2=0.9980–0.9994). The reasonable relative standard deviations (RSDs) from 3.46 to 5.74 (n=3) were also obtained. The enrichment coefficients were calculated to be 17 as the minimum and 20 as the maximum. The obtained limits of detection and limit of quantitation were respectively in range of 0.09–0.19 μg L−1 and 0.32–0.56 μg L−1. Finally, the adsorbent was used to measure the PAHs content of real samples including tap water, river water and brewed tea. The recoveries were between 80.0 %–100.4 % (for tap water) and 91.1 %–100.5 % (for river water) and 83.4 %–102.1 % (for tea sample).

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Section: Introductionmentioning

confidence: 99%

Magnetic Polyeugenol Nanoparticles as a New Sorbent for Solid‐Phase Extraction of Polycyclic Aromatic Hydrocarbons in Environmental Water and Food Samples

2023

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“…Over past few decades, various sample pretreatment techniques, such as Soxhlet extraction, supercritical fluid extraction, ultrasonication-assisted extraction, liquid-phase microextraction and solid phase extraction, were developed for clean-up and enrichment of environmental pollutants [ 9 , 10 , 11 , 12 , 13 ]. Owing to easy operation, excellent adsorption performance and plenty of materials able to be used as sorbents, solid phase-based extraction techniques, including conventional solid phase extraction [ 14 ], dispersive solid phase extraction [ 15 , 16 , 17 ], magnetic solid phase extraction [ 18 , 19 , 20 , 21 ], stir bar sorptive dispersive microextraction [ 22 ] and solid-phase microextraction (SPME) [ 23 , 24 , 25 , 26 ] received considerable attention in environmental and biological analysis.…”

Section: Introductionmentioning

confidence: 99%

Porous Hexagonal Boron Nitride as Solid-Phase Microextraction Coating Material for Extraction and Preconcentration of Polycyclic Aromatic Hydrocarbons from Soil Sample

Zhu

et al. 2022

Nanomaterials

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Sample pretreatment plays important role in the analysis and detection of trace pollutants in complex matrices, such as environmental and biological samples. The adsorption materials of sample pretreatment receive considerable attention, which has a significant effect on the sensitivity and selectivity of the analytical method. In this work, the porous hexagonal boron nitride (h-BN) was utilized as a coating material of solid-phase microextraction (SPME) to extract and preconcentrate polycyclic aromatic hydrocarbons (PAHs) prior to separation and detection with GC-FID. Attributed to the multiple interactions including hydrophobicity, hydrogen bonding and strong π–π interaction, the h-BN coating showed excellent extraction performance for PAHs. Under the optimal conditions, the method showed the linear relationship in the range of 0.1–50 ng mL−1 for acenaphthene, 0.05–50 ng mL−1 for pyrene, and 0.02–50 ng mL−1 for fluorene, phenanthrene and anthracene with a correlation coefficient (R2) not lower than 0.9910. The enrichment factors were achieved between 1526 and 4398 for PAHs with h-BN as SPME fiber coating. The detection limits were obtained in the range of 0.004–0.033 ng mL−1, which corresponds to 0.08–0.66 ng g−1 for soil. The method was successfully applied to analysis of real soil samples. The recoveries were determined between 78.0 and 120.0% for two soil samples. The results showed that h-BN material provided a promising alternative in sample pretreatment and analysis.

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“…Polycyclic aromatic hydrocarbons (PAHs) are a group of persistent organic pollutants (POPs) consisted of two to eight fused aromatic rings and derived from both natural and anthropogenic sources. − The intracellular ingested PAHs might bind to bases of DNA and form adducts, leading to gene mutation and canceration. , Benzo[a]pyrene (BaP) is one of the most carcinogenic PAHs included in the US EPA priority pollutant list . Studies have demonstrated that BaP could induce cytotoxicity, cell proliferation, and DNA damage, − generating repair enzymes in BER pathway .…”

mentioning

confidence: 99%

Development of a Repair Enzyme Fluorescent Probe to Reveal the Intracellular DNA Damage Induced by Benzo[a]pyrene in Living Cells

et al. 2023

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Pollutant exposure causes a series of DNA damage in cells, resulting in the initiation and progression of diseases and even cancers. An investigation of the DNA damage induced by pollutants in living cells is significant to evaluate the cytotoxicity, genotoxicity, and carcinogenicity of environmental exposure, providing critical insight in the exploration of the etiologies of diseases. In this study, we develop a repair enzyme fluorescent probe to reveal the DNA damage caused by an environmental pollutant in living cells by single-cell fluorescent imaging of the most common base damage repair enzyme named human apurinic/apyrimidinic endonuclease 1 (APE1). The repair enzyme fluorescent probe is fabricated by conjugation of an APE1 high affinity DNA substrate on a ZnO2 nanoparticle surface to form a ZnO2@DNA nanoprobe. The ZnO2 nanoparticle serves as both a probe carrier and a cofactor supplier, releasing Zn2+ to activate APE1 generated by pollutant exposure. The AP-site in the DNA substrate of the fluorescent probe is cleaved by the activated APE1, releasing fluorophore and generating fluorescent signals to indicate the position and degree of APE1-related DNA base damage in living cells. Subsequently, the developed ZnO2@DNA fluorescent probe is applied to investigate the APE1-related DNA base damage induced by benzo[a]pyrene (BaP) in living human hepatocytes. Significant DNA base damage by BaP exposure is revealed, with a positive correlation of the damage degree with exposure time in 2–24 h and the concentration in 5–150 μM, respectively. The experimental results demonstrate that BaP has a significant effect on the AP-site damage, and the degree of DNA base damage is time-dependent and concentration-dependent.

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Preparation of Amino-functionalized Guanidinium Ionic Liquid-Modified Magnetic Materials and Application in Solid-Phase Extraction of Pollutants in Water

Cited by 14 publications

References 36 publications

Magnetic Polyeugenol Nanoparticles as a New Sorbent for Solid‐Phase Extraction of Polycyclic Aromatic Hydrocarbons in Environmental Water and Food Samples

Magnetic Polyeugenol Nanoparticles as a New Sorbent for Solid‐Phase Extraction of Polycyclic Aromatic Hydrocarbons in Environmental Water and Food Samples

Porous Hexagonal Boron Nitride as Solid-Phase Microextraction Coating Material for Extraction and Preconcentration of Polycyclic Aromatic Hydrocarbons from Soil Sample

Development of a Repair Enzyme Fluorescent Probe to Reveal the Intracellular DNA Damage Induced by Benzo[a]pyrene in Living Cells

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