Preparation of Anionic Surfactant-Based One-Dimensional Nanostructured Polyaniline Fibers for Hydrogen Storage Applications

Al‐Aoh, Hatem A.; Badi, N.; Roy, Aashis S.; Alsharari, Abdulrhman M.; Wanees, S. Abd El; Albaqami, Abdulrahman; Ignatiev, A.

doi:10.3390/polym15071658

Cited by 5 publications

(2 citation statements)

References 53 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The bands at 2918 cm −1 and 2858 cm −1 are due to CH 2 and CH symmetric stretching in the five-membered pyrrole ring. The band at 1635 cm −1 is assigned to the ring stretching vibration of a C=C bond, while a C-H deformation vibration appeared at 1030 cm −1 [30,31]. The spectrum of the PANI-coated cotton textiles shows a band at 3421 cm −1 that is related to the stretching vibration of the secondary amine (N-H) in PANI.…”

Section: Characterization Of Ppy-coated and Pani-coated Cotton Fabricsmentioning

confidence: 99%

Polypyrrole- and Polyaniline-Coated Cotton Fabrics as Efficient Adsorbents for the Pharmaceutical Water Contaminants Diclofenac and Salicylic Acid

Farghal,

Tawakey,

Amer

et al. 2023

Polymers

View full text Add to dashboard Cite

The emerging pharmaceutical contaminants diclofenac (DCF) and salicylic acid (SA) pose potential hazards to humans and living organisms due to their persistence in water environments. In this work, the conductive polymers polypyrrole (PPY) and polyaniline (PANI) were successfully coated on cotton fabrics, as confirmed by FTIR and SEM measurements. The coated fabrics efficiently removed DCF at pH 5.3 and SA at pH 4, with removal efficiencies that exceeded 90% and 70%, respectively. Adsorption was rapid for most of the tested contaminant–fabric systems and reached equilibrium within 20–30 min. The best adsorption performance for both contaminants was shown on the PPY-coated fabrics, which yielded adsorption capacities of about 65 and 21 mg/g for DCF and SA, respectively. This could be explained by molecular modeling simulations, which mostly estimated higher total cohesive energy densities for adsorption on the PPY-coated fabrics than on the PANI-coated ones. The adsorption mechanism involved both coulombic electrostatic attractions and non-coulombic van der Waals and π-π stacking. The fabrics could be reused for three adsorption–desorption cycles. Immobilization of the conductive polymers on cotton fabrics provides a facile method for their handling and collection during adsorption and regeneration cycles while maintaining their multi-functionality in adsorbing different contaminants.

show abstract

Section: Characterization Of Ppy-coated and Pani-coated Cotton Fabricsmentioning

confidence: 99%

Polypyrrole- and Polyaniline-Coated Cotton Fabrics as Efficient Adsorbents for the Pharmaceutical Water Contaminants Diclofenac and Salicylic Acid

Farghal,

Tawakey,

Amer

et al. 2023

Polymers

View full text Add to dashboard Cite

show abstract

“…Porous metal oxides (NiO, ZnO, Al 2 O 3 , MgO, and TiO 2 ) have recently been investigated for hydrogen storage [19]. The important characteristics of TiO 2 , such as non-toxicity, chemical inertness, low cost, and environmental friendliness, make them suitable for use in a variety of applications such as paints, fuel cells, solar cells, gas sensors, hydrogen storage, antimicrobial materials, and photocatalysis [20][21][22]. There are materials that store hydrogen as hydrides and others that adsorb hydrogen molecules onto their surfaces.…”

Section: Introductionmentioning

confidence: 99%

Enhanced and Proficient Soft Template Array of Polyaniline—TiO2 Nanocomposites Fibers Prepared Using Anionic Surfactant for Fuel Cell Hydrogen Storage

Badi,

Roy,

Al-Aoh

et al. 2023

Polymers

Self Cite

View full text Add to dashboard Cite

Porous TiO2-doped polyaniline and polyaniline nanocomposite fibers prepared by the in situ polymerization technique using anionic surfactant in an ice bath were studied. The prepared nanocomposites were characterized by FTIR spectroscopy and XRD patterns for structural analysis. The surface morphology of the polyaniline and its nanocomposites was examined using SEM images. DC conductivity shows the three levels of conductivity inherent in a semiconductor. Among the nanocomposites, the maximum DC conductivity is 5.6 S/cm for 3 wt.% polyaniline-TiO2 nanocomposite. Cyclic voltammetry shows the properties of PANI due to the redox peaks of 0.93 V and 0.24 V. Both peaks are due to the redox transition of PANI from the semiconductor to the conductive state. The hydrogen absorption capacity is approximately 4.5 wt.%, but at 60 °C the capacity doubles to approximately 7.3 wt.%. Conversely, 3 wt.% PANI—TiO2 nanocomposites have a high absorption capacity of 10.4 wt.% compared to other nanocomposites. An overall desorption capacity of 10.4 wt.% reduced to 96% was found for 3 wt.% TiO2-doped PANI nanocomposites.

show abstract

Synergistic Enhancements of Zn-ZIF with Nano Zinc Oxide for Hydrogen adsorption, energy storage, and photocatalytic technologies

Alsharif,

Darwish,

Alghamdi

et al. 2024

Ceramics International

View full text Add to dashboard Cite

Preparation of Anionic Surfactant-Based One-Dimensional Nanostructured Polyaniline Fibers for Hydrogen Storage Applications

Cited by 5 publications

References 53 publications

Polypyrrole- and Polyaniline-Coated Cotton Fabrics as Efficient Adsorbents for the Pharmaceutical Water Contaminants Diclofenac and Salicylic Acid

Polypyrrole- and Polyaniline-Coated Cotton Fabrics as Efficient Adsorbents for the Pharmaceutical Water Contaminants Diclofenac and Salicylic Acid

Enhanced and Proficient Soft Template Array of Polyaniline—TiO2 Nanocomposites Fibers Prepared Using Anionic Surfactant for Fuel Cell Hydrogen Storage

Synergistic Enhancements of Zn-ZIF with Nano Zinc Oxide for Hydrogen adsorption, energy storage, and photocatalytic technologies

Contact Info

Product

Resources

About