2006
DOI: 10.1002/masy.200690109
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Preparation of Aqueous Polyurethane Dispersions Using Aromatic Diisocyanate

Abstract: Aqueous polyurethane dispersions were prepared by the reaction of hydroxyl‐terminated poly(ethylene adipate), ethylene glycol, dimethylol propionic acid and aromaic diisocyante, 4,4′‐diphenylmethane diisocyanate. The influence of molecular weight of oligoester and molar ratio between isocyanate and hydroxyl groups (NCO/OH) in the prepolymerization step were investigated. Molecular weight, particle size and particle size distribution were measured and compared. It was verified that the molecular weight increase… Show more

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Cited by 10 publications
(8 citation statements)
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“…It led to the decrease of hydrophilicity of polyurethane particles. The viscosity of the PU dispersions was in the order of PB14 > PB23 > PB32 14–16…”
Section: Resultsmentioning
confidence: 99%
“…It led to the decrease of hydrophilicity of polyurethane particles. The viscosity of the PU dispersions was in the order of PB14 > PB23 > PB32 14–16…”
Section: Resultsmentioning
confidence: 99%
“…Compared to the prepolymers, the molecular weights of the chain-extended poly(urethane urea)s (PUUs) were approximately twice as high. Compared to the conventional chain-extended PUU dispersions [35][36][37], these M n values are still rather low. The M n(PUD) values seem to increase with decreasing DDI/EELDI molar ratio.…”
Section: Puds Prepared From Ddi Eeldi Is and Dmpamentioning
confidence: 84%
“…The adhesion agent is needed to fabricate composites in hot press molding . Aqueous adhesives, such as acrylic, polyurethane (PU), epoxy etc., are able to substitute for solvent adhesives because of their exceptional environmental friendly, nontoxic, nonflammable, and high solid content, which are widely used in the fields of building, packaging, and transportation . K. Hasan et al prepared the luffa/epoxy resin composite to test the sound absorption property by using a hydraulic press.…”
Section: Introductionmentioning
confidence: 99%