Preparation of BaBi1/2Sb1/2O3 from Ba(COO)2·0.5H2O and Sb(COO)2(OH) oxalates and Bi2O3 oxide

Crystal Structure and Thermal Behavior of SbC2O4OH and SbC2O4OD

“…They react to ternary compounds like ZnSb2O6, at about the same temperatures as the mixtures of the binary oxides (1073 K [22]) do, way above the decomposition temperature of SbC2O4OH. Similar behavior was observed for the reaction of SbC2O4OH, with barium oxalate hydrate and bismuth oxide to BaBi1/2Sb1/2O3 [9]. The advantage of a low decomposition temperature is thus only an apparent one for the precursor-based synthesis of antimonates.…”

“…It decomposes within one step at 563 K to antimony(III) oxide [7,8]. SbC 2 O 4 OH can be used for the preparation of antimony containing compounds, i.e., mixed crystal oxides such as BaBi 1/2 Sb 1/2 O 3 [9]. The low decomposition temperature, simple synthesis and stable composition seem to be attractive properties for usage as a precursor for antimony-based materials.…”

Synthesis of BaCeO3 and BaCe0.9Y0.1O3−δ from mixed oxalate precursors

“…6 For Ce-oxalate, the H 2 O loss occurred at 100-190 • C and further decomposition into CeO 2 was presented by the exothermic peak at 295 • C. 7 Y-oxalate sample presented H 2 O loss at 130-246 • C and decomposition into Y 2 O 3 at 400-687 • C.…”

Crystal structure of antimony oxalate hydroxide, Sb(C2O4)OH

“…The white solid was washed several times with de-ionized water and dried at 110 °C for 3 h. A 96% yield was obtained. The compound has been prepared previously by reaction of oxalic acid dihydrate and SbCl 3 (Korzun et al , 2005; Karlov et al , 1983; Ambe, 1975).…”