2013
DOI: 10.1002/app.39490
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Preparation of chloromethylated and aminated gel‐type poly(styrene‐co‐divinylbenzene) microparticles with controlled degree of functionalization

Abstract: The possibility of adjusting the degree of hydrophilic functionalization in polymeric microparticles with a hydrophobic skeleton makes it possible to obtain adsorbents and catalyst microparticles that may show better performance. In this regard, in this study, gel‐type poly(styrene‐co‐divinyl benzene) microparticles were chloromethylated and subsequently aminated, and the quantitative effect of the chloromethylation reaction conditions on the final degree of functionalization achieved were examined. In the chl… Show more

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Cited by 6 publications
(2 citation statements)
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“…Specifically, chelating resins are an important category of adsorbent materials 3 – 9 . The majority of chelating resins consist of polystyrene beads, but a toxic chloromethylation reaction is necessary to make chelating resins from polystyrene 17 , 18 . Accordingly, research related to the production of eco-friendly chelating resins has received much attention 19 , 20 .…”
Section: Introductionmentioning
confidence: 99%
“…Specifically, chelating resins are an important category of adsorbent materials 3 – 9 . The majority of chelating resins consist of polystyrene beads, but a toxic chloromethylation reaction is necessary to make chelating resins from polystyrene 17 , 18 . Accordingly, research related to the production of eco-friendly chelating resins has received much attention 19 , 20 .…”
Section: Introductionmentioning
confidence: 99%
“…Many polymeric materials containing active chloride have been used as intermediate products for introducing a number of functional groups for various applications [1,2]. Therefore, methods have been developed to analyze chloride e.g.…”
Section: Introductionmentioning
confidence: 99%