Preparation of COF2 using CO2 and F2 in the electrochemical cell with PbSnF4 as a solid electrolyte

Thermochemical Parameters of CHFO and CF2O

“… C O F 2 + C H 3 + S b F 6 − → C F 3 O C H 3 + S b F 5 The question is thus whether the relative basicities or nucleophilicities of the oxygen atoms in COF 2 and CF 3 OH differ significantly. Since the relative affinities for CH 3 + and H + of COF 2 and CF 3 OH should be the same and we now have accurate proton affinities, calculated by the same methods at the same level of theory, for both compounds, it is interesting to compare these proton affinities. Our calculated proton affinities of oxygen in COF 2 and CF 3 OH are 148.8 and 147.5 kcal/mol, respectively.…”

“…CF 2 O is the main product from the gradual decomposition of perfluoro polyalkyl ethers . Recent experiments demonstrated that CF 2 O can be formed from reactions of CO 2 with F 2 under various conditions.…”

Effect of Aliovalent Dopants on the Electrophysical Properties of Mechanochemically Sythesized KSn₂F₅

“…At the present time, there are significant interest of the researchers attracted by searching of new functional materials for alternative energy sources, which would be effectually increase the present traditional electrochemical converting and energy-converting devices [1][2][3][4][5][6][7]. Fluorides, which show high value of ionic conductivity among the anionic conductors due to the small size of the Fand presence of elements with an unshared electron pair (e.g.…”

“…Fluorides, which show high value of ionic conductivity among the anionic conductors due to the small size of the Fand presence of elements with an unshared electron pair (e.g. Sn) are found to be useful in following solid state ionic devices: solid state batteries, gas sensors, electrochromic and memory devices, solid state capacitors [4][5][6]. High ionic polarizability properties of the Pb + and Li + could make beneficial effect on the charge transfer [8][9][10][11][12].…”