Preparation of Covalent and Solvent-resistance Colored Latex Particles and Its Application on Cotton Fabric

Abstract

Conventional colored latex particles have poor solvent resistance due to the absence of chemical bonds between the dye and polymer component, resulting in staining and greatly restricting its application. In this research, the disperse dye was chemically bonded to the polymer to prepare covalent and solvent-resistance colored latex particles. Firstly, C.I. Disperse Red 60, as a common disperse dye in industry, was modified by acryloyl chloride (amidation reaction) for the purpose of introducing the C=C bonds. The structure of modified C.I. Disperse Red 60 was confirmed by 1 HNMR, FTIR and elemental analysis and its spectral property was also evaluated. Then the covalent colored latex particles were synthesized via miniemulsion copolymerization of styrene (St) and ethyl acrylate (EA) in presence of modified C.I. Disperse Red 60 monomer. Results of FTIR, TG, DSC and TEM indicated that the covalent colored latex particles were successfully prepared. By using UV-spectroscopy, the solvent resistance of the colored latex membranes in petroleum ether, hexane, cyclohexane, and ethanol was monitored, respectively. Slight change of the absorption was detected for 10 days, which verified the excellent solvent resistance of covalent colored latex membranes. Finally, the prepared colored latex particles were applied on cotton printing in the absence of binder. The results showed that the colored latex particles printed fabric had superior rubbing fastness and soft hand feel.

Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

“…It was noted that two decomposition steps around 276.5 and 447.3 °C were found in the prepared CLP@PS. In the first stage, about 10.1% of the weight loss was caused by the decomposition of AHAQ and some small molecular substances . At the second stage of 447.3 °C, about 86.7% of weight losses resulted from the decomposition of polymer molecular chains …”

Dyes as Labels in Biosensing

“…There are three ways to prepare colored latex particles by dying latex particles with different types of dyes molecules: (1) co-polymerization of polymer monomer with dyes; (2) cross-linking the dyes on particles surface by covalent bonds; (3) physical embedding or absorption dyes in particles. After the dying, usually dyes on the surface are removed in order to functionalize the active groups (sulfhydryl groups, amino groups and carboxyl groups) on the latex particles for further labeling the biomolecules [28].…”