In
the present study, density functional theory (DFT) has been
used in simulating and calculating the molecular geometries of differently
structured polyols (within a water phase), as well as the weak interactions
between these polyols and the water molecules. Furthermore, low field
nuclear magnetic resonance (LF-NMR) has been used in studying the
transverse relaxation times of different polyols, in addition to their
(20.00 wt %) fluidity in an aqueous environment. Moreover, the influence
of polyols, with different molecular structures, on the ink fluidity,
was also explored. A bubble pressure tensiometer was also used to
characterize the surface tension of the aqueous polyol (20.00 wt %)
solution, the sodium dodecyl sulfate (SDS, 0.50 wt %) solution, and
the ink. This was made to clarify the influence of polyol and SDS
on the surface tension of ink. In addition, the particle size, zeta
potential, pH value, viscosity, and rheological properties of the
ink, were also investigated. The resulting data showed that polyols
have certain effects on the particle size, stability, and viscosity
of the ink. The jetting performances of different polyol inks were,
under certain conditions of the inkjet drive waveform, also explored.
The results showed that the fluidity, viscosity, and surface tension
of the ink will render a certain influence on the inkjet performances.
The prepared polyol ink was thereafter used for polyester fabric printing,
and the contour sharpness and color fastness of the printed fabric
were accordingly evaluated. The data showed that the increase in ink
viscosity, and decrease in fluidity, promote the improvement in contour
sharpness. In addition, the printed fabric demonstrated an excellent
color fastness.