Preparation of epoxy-functionalized methyl methacrylate-butadiene-styrene core-shell particles and investigation of their dispersion in polyamide-6

Aerdts, AM Annemieke; Groeninckx, Gabriël; Zirkzee, HF Hennie; Aert, van Ham Huub; Geurts, JM John

doi:10.1016/s0032-3861(96)01003-8

Cited by 19 publications

(10 citation statements)

References 22 publications

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“…A solution to this problem is the addition of MBS copolymers (methyl methacrylatebutadiene-styrene) or MABS (methyl methacrylateacrylonitrile-butadiene-styrene), which do ot change the PMMA transparency because the refraction index of these elastomers is close to the PMMA. Studies in literature show that the addition of MBS to PMMA does not change its transparency and improves its mechanical properties, especially elongation at break and impact strength [7,[13][14][15][16][17] .…”

Section: Introductionmentioning

confidence: 99%

Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization

et al. 2015

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SbstractIn this work, the rheological, mechanical and morphological behavior of immiscible blend poly (methyl methacrylate) with elastomeric particles (PMMA elast ) and post-consumer poly (ethylene terephthalate) (PET) with and without the use of the interfacial compatibilizer poly (methyl methacrylate-co-glycidyl methacrylate-co-ethyl acrylate) (MGE) was studied. The significant increase in torque presented in rheological analyses has shown a indication of chemical reactions between the epoxy group of MGE with end groups of PET chains and also with the elastomeric phase of PMMA elast . The increased concentration of PET yielded an increase in maximum strength and elasticity modulus and a decrease in elongation at break. The PMMA elast /PET binary blend (50/50 wt%) and PMMA elast /PET/MGE compatibilized blend (65/30/5 wt%) showed pronounced results in elongation at break compared to PMMA elast , whereas, in the first results were due to the evidence of a co-continuous morphological structure and in the second, due to the efficiency of the dual reactive interfacial compatibilization of PMMA elast /PET blends. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses showed that PMMA elast /PET/MGE blends exhibit complex phase morphology due to the presence of elastomeric particles in the PMMA elast copolymer and in the use of MGE terpolymer.

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Section: Introductionmentioning

confidence: 99%

Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization

et al. 2015

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“…The most important groups of impact modifiers are elastomers [17], styrene block copolymers, polyolefins, polybutenes, core-shell rubbers [18], and acrylic elastomers [16]. To improve the compatibility between polymer/polymer and/or polymer/inorganic filler phases, the impact modifiers are frequently functionalized.…”

Section: Introductionmentioning

confidence: 99%

Hybrid electro-conductive composites with improved toughness, filled by carbon black

Novák

Krupa

Janigová

2005

Carbon

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“…coatings [1,2] and engineering plastics [3][4][5][6][7][8], require high impact strength. The paint of a car, for instance, should withstand being hit by a piece of gravel without film rupture.…”

Section: Introductionmentioning

confidence: 99%

About morphology in ethylene–propylene(-diene) copolymers-based latexes

Tillier

Meuldijk

Höhne

et al. 2005

Polymer

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Preparation of epoxy-functionalized methyl methacrylate-butadiene-styrene core-shell particles and investigation of their dispersion in polyamide-6

Cited by 19 publications

References 22 publications

Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization

Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization

Hybrid electro-conductive composites with improved toughness, filled by carbon black

About morphology in ethylene–propylene(-diene) copolymers-based latexes

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