2023
DOI: 10.1002/marc.202300084
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Preparation of Ferrocene‐Terminated Dendrimers for the Thermal Decomposition of Ammonium Perchlorate

Abstract: As a common oxidizer, ammonium perchlorate (AP) is an important component in composite solid propellants (CSPs). Ferrocene (Fc)‐based compounds are often selected as burning rate catalysts (BRCs) to catalyze AP decomposition owing to their excellent catalytic behavior. However, one of the drawbacks of Fc‐based BRCs is migration in CSPs. In this study, five Fc‐terminated dendrimers are designed and synthesized to improve the anti‐migration properties, and their chemical structures are confirmed systemically by … Show more

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Cited by 6 publications
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“…Ammonium perchlorate (AP, NH 4 ClO 4 ) is a commonly used oxidizer for composite solid propellants (CSPs), , and its thermal decomposition characteristic is closely related to the propellant combustion performance . Therefore, the thermal decomposition characteristic of AP was widely studied. There are two stages for AP thermal decomposition, , namely, low-temperature decomposition (LTD, <350 °C) and high-temperature decomposition (HTD, >350 °C). In the LTD stage, the main decomposition products of AP are ammonia (NH 3 ) and perchloric acid (HClO 4 ).…”
Section: Introductionmentioning
confidence: 99%
“…Ammonium perchlorate (AP, NH 4 ClO 4 ) is a commonly used oxidizer for composite solid propellants (CSPs), , and its thermal decomposition characteristic is closely related to the propellant combustion performance . Therefore, the thermal decomposition characteristic of AP was widely studied. There are two stages for AP thermal decomposition, , namely, low-temperature decomposition (LTD, <350 °C) and high-temperature decomposition (HTD, >350 °C). In the LTD stage, the main decomposition products of AP are ammonia (NH 3 ) and perchloric acid (HClO 4 ).…”
Section: Introductionmentioning
confidence: 99%