The novel solid NaXe nanoclusters were prepared. Measurements and calculations indicated that solid NaXe nanocluster has easily vibration- dissociated ground state and stable excited state to emit UV radiation. In the meanwhile the solid nanocluster NaXe retains fcc position within the host NaCl matrix. Therefore,the integrated ultraviolet(UV)-micro-excimer-laser-matrix can be prepared by using solid NaXe nanoclusters.