Preparation of Highly Energetic Coordination Compounds with Rich Oxidants and Lower Sensitivity Based on Methyl Groups

A novel energetic pyridine-2-carbohydrazide copper perchlorate complex: synthesis, cationic ligand structure and properties

“…To test the thermal stability of ECCs-1, TG and DTA curves were tested with a heating rate of 5 °C min −1 , under a nitrogen atmosphere. The test results showed that the peak thermal decomposition temperature of ECCs-1 was 215.6 °C, which was higher than those of the previously reported [Cu(PZCA) 2 ](ClO 4 ) 2 , 25 [Cu-(HDMPZCA) 2 (ClO 4 ) 2 ](ClO 4 ) 2 ·2H 2 O, 26 and Cu(FRCA) 2 (H 2 O)(ClO 4 ) 2 . 27 The reason may be the low enthalpy of pyridine ring formation, which was more stable than other heterocyclic ligands.…”