Preparation of Highly Heat–Resistant Sm–Fe–N Magnetic Powder by Reduction–Diffusion Process

Abstract

We previously described the preparation of Mn-or Cr-containing coreshell SmFeN powders exhibiting high thermal stability by a reductiondiffusion process, in which powder mixtures of Sm 2 Fe 17 , Sm 2 O 3 , Mn 3 O 4 or Cr 2 O 3 , and Ca were annealed and nitrided followed by the removal of residual CaO by washing with ethylene glycol in a glove box. We also found that SmFeN powder prepared by this process showed high heat resistance even without Mn or Cr addition. In the present work, we investigated the effects of the washing solvent and atmosphere on the coercivity, heat resistance, and microstructure of SmFeN powders. The heat resistance of the SmFeN powders was strongly dependent on their O content. Washing with ethylene glycol rather than water effectively suppressed oxidation during washing. Furthermore, the washing atmosphere also affected the increase in O content of the powders. The SmFeN powder washed with ethylene glycol in a glove box showed high heat resistance and the same microstructure before and after the heat resistance test. In contrast, the powder washed with water in air exhibited low heat resistance owing to the occurrence of ¡-Fe precipitation during the heat resistance test.