A series of barium doped LaMnO3 perovskite nano catalysts were synthesized using the citric acid sol gel method. The prepared nano catalysts were characterized using the various characterization techniques such as XRD, ICPAES, FTIR, SEM, HRTEM, TPR and BET. The Xrd results showed the purity of the prepared catalyst as no segregated phases were observed and also confirming the crystallinity of the prepared catalyst. The surface area achieved in this experiment presented one of the highest reported in literature. The doping of the perovskite catalysts helps in increasing the surface area. The ICPAES results shows the efficiency of the preparation method adopted. The catalytic evaluation shows that upon introduction of Ba into the perovskite structure, the catalytic performance of the catalyst were greatly increased with LBM3 giving the lowest T50 at 550°C