Preparation of Li4Ti5O12 electrode thin films by a mist CVD process with aqueous precursor solution

Tadanaga, Kiyoharu; Yamaguchi, Akihiro; Hayashi, Akitoshi; Tatsumisago, Masahiro; Mosa, Jadra; Aparicio, Mario

doi:10.1016/j.jascer.2014.11.003

Cited by 13 publications

(11 citation statements)

References 18 publications

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“…For instance, Tadanaga et al . reported a novel mist CVD method for the preparation of Li 4 Ti 5 O 12 thin film . Furthermore, Li 4 Ti 5 O 12 materials with the favorable carbon coating have been also synthesized via a CVD technique, and therefore a good electrochemical performance can be easily reached .…”

Section: Synthesis Methods Of Li4ti5o12mentioning

confidence: 99%

Li₄Ti₅O₁₂ Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Chen

et al. 2017

The Chemical Record

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Spinel Li Ti O , known as a zero-strain material, is capable to be a competent anode material for promising applications in state-of-art electrochemical energy storage devices (EESDs). Compared with commercial graphite, spinel Li Ti O offers a high operating potential of ∼1.55 V vs Li/Li , negligible volume expansion during Li intercalation process and excellent thermal stability, leading to high safety and favorable cyclability. Despite the merits of Li Ti O been presented, there still remains the issue of Li Ti O suffering from poor electronic conductivity, manifesting disadvantageous rate performance. Typically, a material modification process of Li Ti O will be proposed to overcome such an issue. However, the previous reports have made few investigations and achievements to analyze the subsequent processes after a material modification process. In this review, we attempt to put considerable interest in complete device design and assembly process with its material structure design (or modification process), electrode structure design and device construction design. Moreover, we have systematically concluded a series of representative design schemes, which can be divided into three major categories involving: (1) nanostructures design, conductive material coating process and doping process on material level; (2) self-supporting or flexible electrode structure design on electrode level; (3) rational assembling of lithium ion full cell or lithium ion capacitor on device level. We believe that these rational designs can give an advanced performance for Li Ti O -based energy storage device and deliver a deep inspiration.

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Section: Synthesis Methods Of Li4ti5o12mentioning

confidence: 99%

Li₄Ti₅O₁₂ Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Chen

et al. 2017

The Chemical Record

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“…LTO thin films have been grown via PLD [346][347][348][349], sputtering [350,351], sol-gel [352,353] and CVD processes [354]. Deng et al [348] reported the growth of the ( 111)-oriented LTO thin films on Pt/Ti/SiO 2 /Si substrates via PLD, showing a discharge capacity of 157 mAh/g after 10 cycles with a constant current density of 10 µA/cm 2 .…”

Section: Anodesmentioning

confidence: 99%

Advances in Materials Design for All-Solid-state Batteries: From Bulk to Thin Films

Yang

Abraham

et al. 2020

Applied Sciences

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All-solid-state batteries (SSBs) are one of the most fascinating next-generation energy storage systems that can provide improved energy density and safety for a wide range of applications from portable electronics to electric vehicles. The development of SSBs was accelerated by the discovery of new materials and the design of nanostructures. In particular, advances in the growth of thin-film battery materials facilitated the development of all solid-state thin-film batteries (SSTFBs)—expanding their applications to microelectronics such as flexible devices and implantable medical devices. However, critical challenges still remain, such as low ionic conductivity of solid electrolytes, interfacial instability and difficulty in controlling thin-film growth. In this review, we discuss the evolution of electrode and electrolyte materials for lithium-based batteries and their adoption in SSBs and SSTFBs. We highlight novel design strategies of bulk and thin-film materials to solve the issues in lithium-based batteries. We also focus on the important advances in thin-film electrodes, electrolytes and interfacial layers with the aim of providing insight into the future design of batteries. Furthermore, various thin-film fabrication techniques are also covered in this review.

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“…Many deposition methods have been applied to synthesize Li 4 Ti 5 O 12 film anodes, including sol-gel [62,63], magnetron sputtering [64,65], spray pyrolysis [66], aerosol [67] and CVD [68].…”

Section: Anode Materialsmentioning

confidence: 99%

Metal-organic chemical vapor deposition enabling all-solid-state Li-ion microbatteries: A short review

2017

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For powering small-sized electronic devices, allsolid-state Li-ion batteries are the most promising candidates due to its safety and allowing miniaturization. Thin film deposition methods can be used for building new all-solid-state architectures. Well-known deposition methods are sputter deposition, pulsed laser deposition, sol-gel deposition, atomic layer deposition, etc. This review summarizes thin film storage materials deposited by metal-organic chemical vapor deposition (MOCVD) for all-solid-state Li-ion batteries. The deposition parameters strongly influence the quality of the films, such as surface morphology, composition, electrochemical stability and cycling performance. Some materials have been successfully deposited by MOCVD into 3D-structured substrates, revealing conformal, homogeneous and high performance battery properties.

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Preparation of Li₄Ti₅O₁₂ electrode thin films by a mist CVD process with aqueous precursor solution

Cited by 13 publications

References 18 publications

Li₄Ti₅O₁₂ Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Li₄Ti₅O₁₂ Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Advances in Materials Design for All-Solid-state Batteries: From Bulk to Thin Films

Metal-organic chemical vapor deposition enabling all-solid-state Li-ion microbatteries: A short review

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Preparation of Li4Ti5O12 electrode thin films by a mist CVD process with aqueous precursor solution

Cited by 13 publications

References 18 publications

Li4Ti5O12 Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Li4Ti5O12 Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Advances in Materials Design for All-Solid-state Batteries: From Bulk to Thin Films

Metal-organic chemical vapor deposition enabling all-solid-state Li-ion microbatteries: A short review

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Product

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Preparation of Li₄Ti₅O₁₂ electrode thin films by a mist CVD process with aqueous precursor solution

Li₄Ti₅O₁₂ Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices

Li₄Ti₅O₁₂ Anode: Structural Design from Material to Electrode and the Construction of Energy Storage Devices