Preparation of lignin-based vinylogous urethane vitrimer materials and their potential use as on-demand removable adhesives

Liu, Jian; Pich, Andrij; Bernaerts, Katrien V.

doi:10.1039/d3gc02799f

Cited by 11 publications

(2 citation statements)

References 58 publications

(87 reference statements)

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“…The results in the Fig. S4(a)† show that an increase in lignin content in the material increases the strength of the material (A, 30 B, 31 C, 32 D 33 and E 34 ) and correspondingly decreases the strain. Compared to lignin-based vitrimers synthesized with other chemical systems, this study exhibits a pronounced advantage in stain.…”

Section: Resultsmentioning

confidence: 97%

Preparation of lignin-based imine vitrimers and their potential application as repairable, self-cleaning, removable and degradable coatings

Liu,

Bernaerts

2024

J. Mater. Chem. A

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Section: Resultsmentioning

confidence: 97%

Preparation of lignin-based imine vitrimers and their potential application as repairable, self-cleaning, removable and degradable coatings

Liu,

Bernaerts

2024

J. Mater. Chem. A

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“…The versatility of vitrimers is underscored by their unique combination of stability and processability, leading to applications in reprocessable [34,35] and recyclable polymers [36,37] that contribute to sustainable practices. Additionally, vitrimers find use in coatings [38], adhesives [39,40], and reshapable polymers [41,42], showcasing easy processability for adjustments and repairs. Their shape memory properties offer utility in 3D printing [43][44][45].…”

Section: Introductionmentioning

confidence: 99%

Vitrimer Nanocomposites for Highly Thermal Conducting Materials with Sustainability

Hong,

Goh

2024

Polymers

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Vitrimers, as dynamic covalent network polymers, represent a groundbreaking advancement in materials science. They excel in their applications, such as advanced thermal-conductivity composite materials, providing a sustainable alternative to traditional polymers. The incorporation of vitrimers into composite fillers enhances alignment and heat passway broadly, resulting in superior thermal conductivity compared to conventional thermosetting polymers. Their dynamic exchange reactions enable straightforward reprocessing, fostering the easy reuse of damaged composite materials and opening possibilities for recycling both matrix and filler components. We review an overview of the present advancements in utilizing vitrimers for highly thermally conductive composite materials.

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Dynamic Covalent Chemistry of Enamine‐Ones: Exploring Tunable Reactivity in Vitrimeric Polymers and Covalent Organic Frameworks

Jadhav,

Dhokale,

Saeed

et al. 2024

ChemSusChem

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Dynamic covalent chemistry (DCC) has revolutionized the field of polymer science by offering new opportunities for the synthesis, processability, and recyclability of polymers as well as in the development of new materials with interesting properties such as vitrimers and covalent organic frameworks (COFs). Many DCC linkages have been explored for this purpose, but recently, enamine‐ones have proven to be promising dynamic linkages because of their facile reversible transamination reactions under thermodynamic control. Their high stability, stimuli‐responsive properties, and tunable kinetics make them promising dynamic cross‐linkers in network polymers. Given the rapid developments in the field in recent years, this review provides a critical and up‐to‐date overview of recent developments in enamine‐one chemistry, including factors that control their dynamics. The focus of the review will be on the utility of enamine‐ones in designing a variety of processable and self‐healable polymers with important applications in vitrimers and recyclable closed‐loop polymers. The use of enamine‐one linkages in crystalline polymers, known as COFs and their applications are also summarized. Finally, we provide an outlook for future developments in this field.

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Preparation of lignin-based vinylogous urethane vitrimer materials and their potential use as on-demand removable adhesives

Abstract: Conventional thermosets rely on petrochemical products, and cannot be reprocessed, recycled, or reshaped under mild conditions owing to their permanent, highly crosslinked structure. Although some of these materials are down-cycled...

Cited by 11 publications

References 58 publications

Preparation of lignin-based imine vitrimers and their potential application as repairable, self-cleaning, removable and degradable coatings

Preparation of lignin-based imine vitrimers and their potential application as repairable, self-cleaning, removable and degradable coatings

Vitrimer Nanocomposites for Highly Thermal Conducting Materials with Sustainability

Dynamic Covalent Chemistry of Enamine‐Ones: Exploring Tunable Reactivity in Vitrimeric Polymers and Covalent Organic Frameworks

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