2019
DOI: 10.1038/s41428-019-0244-x
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Preparation of multifunctional glycopolymers using double orthogonal reactions and the effect of electrostatic groups on the glycopolymer–lectin interaction

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Cited by 3 publications
(3 citation statements)
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“…Another route to bifunctional copolymers was explored by Oh et al [ 226 ] who synthesized a triblock copolymer, poly[(trimethylsilyl-propargyl methacrylate)- b -(triethylene glycol monoethyl ether monomethacrylate- stat -glycidyl methacrylate)- b -(trimethylsilyl propargyl methacrylate), in three steps with 4-cyano-4-(phenyl carbonothioylthio) pentanoic acid as a RAFT agent. The copolymer with a total M n = 23 kg⋅mol − 1 and Ð = 1.34 contained 55 protected alkyne group in the terminal blocks and 13 reactive epoxy groups in the middle block.…”
Section: Post-modification Of Side-group Approachmentioning
confidence: 99%
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“…Another route to bifunctional copolymers was explored by Oh et al [ 226 ] who synthesized a triblock copolymer, poly[(trimethylsilyl-propargyl methacrylate)- b -(triethylene glycol monoethyl ether monomethacrylate- stat -glycidyl methacrylate)- b -(trimethylsilyl propargyl methacrylate), in three steps with 4-cyano-4-(phenyl carbonothioylthio) pentanoic acid as a RAFT agent. The copolymer with a total M n = 23 kg⋅mol − 1 and Ð = 1.34 contained 55 protected alkyne group in the terminal blocks and 13 reactive epoxy groups in the middle block.…”
Section: Post-modification Of Side-group Approachmentioning
confidence: 99%
“… Synthetic route to bifunctional copolymers combining RAFT polymerization, azide–alkyne, and thiol–ene click reactions [ 226 ]. …”
Section: Figures Schemes and Tablesmentioning
confidence: 99%
“…SBAPs take various nano morphologies such as micelles, microgels, and nanoparticles [ 38 ] and are considered as less-immunogenic and easily tunable and biodegradable. Synthetic SBAPs are the results of either polymerization of glycosylated comonomers or various polymer backbone can be conjugated with variety of sugar molecules forming polymers with specific physico-chemical properties such as varying degree of charge (positive, negative or non-ionic) or hydrophobicity [ 39 ]. Chemically-modified inulin (high molecular weight fructo-oligosaccharides (FOS) or fructans) with pentyl, benzyl, hexyl, have been shown to effectively solubilized synthetic lipid bilayers composed of DMPC:DPMG (7:3) and form particles with ~10 nm hydrodynamic radius.…”
Section: Natural Biopolymers As Tools For Spontaneous Reconstruction Of Biomembrane Assembliesmentioning
confidence: 99%