Preparation of Pd-PS, Pd-PSB and Pd-PSC nanoparticles by γ-irradiation and their catalytic efficiency in Sonogashira coupling reaction

Radiolytic Preparation of Electrocatalysts with Pt‐Co and Pt‐Sn Nanoparticles for a Proton Exchange Membrane Fuel Cell

“…Pt-M/VC catalysts were successfully prepared by a one-step radiation-induced reduction (RIR) process. Diverse papers have reported that the mechanism of RIR could be generally proven by the following equation [22][23][24][25][26][27][28]:…”

Sonogashira Reactions Using Nanocatalysts

“…They gave comparable yields as commercial 10% palladium on charcoal, although no recycling experiments were reported for this reaction. 69 In addition, Pd-NPs were generated in a solution of Pd(PPh 3 ) 4 and styrene/divinylbenzene under an oxygen atmosphere, followed by radical polymerization. 70 The resulting polystyrene-immobilized Pd-NPs were used as catalysts (1 mol% Pd) in the coupling of methyl p-iodobenzoate with phenylacetylene, using triethylamine as base in DMF at 110 • C. The reaction required the presence of Cu(I) iodide as a cocatalyst.…”

Facile synthesis of novel Pt–Ru@PPy–MWNT electrocatalysts for direct methanol fuel cells

“…In the presence of 50 ppm of the Ag-SiO 2 particles, the Salmonella enterica serovar Typhimurium grew at a much slower rate [20]. In another approach, we have deposited Pd nanoparticles on the surface of polystyrene by c-irradiation and the composite was used as the catalyst for Sonogashira reaction [21]. The above studies encouraged us to use c-radiation for the preparation of novel catalyst composites.…”