Preparation of polyaniline/graphene oxide nanocomposite for the application of supercapacitor

Gui, Dayong; Liu, Chunliang; Chen, Fengying; Liu, Jianhong

doi:10.1016/j.apsusc.2014.04.007

Cited by 158 publications

(54 citation statements)

References 29 publications

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“…Nevertheless, the residual oxygenated groups of rGO sheets do not deprive completely rGO of the unique electrical and mechanical properties of graphenes [36][37]. As a consequence this material can be used for device applications, preparation of graphene-based composites [38][39][40][41][42], thin films and paper like materials [43].…”

Section: Introductionmentioning

confidence: 99%

Effect of hydrothermal reaction time and alkaline conditions on the electrochemical properties of reduced graphene oxide

Vermisoglou

Giannakopoulou

Romanos

et al. 2015

Applied Surface Science

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Section: Introductionmentioning

confidence: 99%

Effect of hydrothermal reaction time and alkaline conditions on the electrochemical properties of reduced graphene oxide

Vermisoglou

Giannakopoulou

Romanos

et al. 2015

Applied Surface Science

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“…These diversities in graphene enable efficient modulation of interfacial adhesion and enhance its compatibility with number of polymers [12], [13], [14], [15], [16], [17], [18], [19] such as polyaniline, polylactic acid, polycaprolactone, PEG etc. In general, graphene production methods can be categorized as two a) bottom-up methods (e.g.…”

Section: Introductionmentioning

confidence: 99%

Thermally conductive thin films derived from defect free graphene-natural rubber latex nanocomposite: Preparation and properties

George

Sisupal

Tomy

et al. 2017

Carbon

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Commercially useful rubber products viz. gloves, condoms, tyres, and rubber hoses used in high temperature environments, etc., require efficient thermal conductivity, which increases the lifetime of these products. Graphene can fetch this property, if it is effectively incorporated into the rubber matrix. The great challenge in preparing graphene-rubber nanocomposites is formulating a scalable method to produce defect free graphene and its homogeneous dispersion into polymer matrices through an aqueous medium. Here, we used a simple method to produce defect free few layer (2–5) graphene, which can be easily dispersed into natural rubber (NR) latex without adversely affecting its colloidal stability. The resulting new composite showed large increase in thermal conductivity (480–980%) along with 40% increase in tensile properties and 60% improvement in electrical conductivity. This study provides a novel and generalized approach for the preparation of graphene based thermally conductive rubber nanocomposites.

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“…Carbon materials [10][11][12][13], transition metal oxides [14] and conducting polymers [15][16][17][18] are the three main types of greatly investigated electrode materials. Recently, polyaniline (PANI) has drawn much attention in electrochemical studies owing to its excellent properties such as low cost, ability to easily form various nanostructures, good biocompatibility and environmental stability [19,20].…”

Section: Introductionmentioning

confidence: 99%

Fabrication of graphene foam supported carbon nanotube/polyaniline hybrids for high-performance supercapacitor applications

Yang¹,

Wang²,

Xu³

et al. 2014

2D Mater.

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A large-scale, high-powered energy storage system is crucial for addressing the energy problem. The development of high-performance materials is a key issue in realizing the grid-scale applications of energystorage devices. In this work, we describe a simple and scalable method for fabricating hybrids (graphenepyrrole/ carbon nanotube-polyaniline (GPCP)) using graphene foam as the supporting template. Graphene-pyrrole (G-Py) aerogels are prepared via a green hydrothermal route from two-dimensional materials such as graphene sheets, while a carbon nanotube/polyaniline (CNT/PANI) composite dispersion is obtained via the in situ polymerization method. The functional nanohybrid materials of GPCP can be assembled by simply dipping the prepared G-py aerogels into the CNT/PANI dispersion. The morphology of the obtained GPCP is investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), which revealed that the CNT/PANI was uniformly deposited onto the surfaces of the graphene. The as-synthesized GPCP maintains its original three-dimensional hierarchical porous architecture, which favors the diffusion of the electrolyte ions into the inner region of the active materials. Such hybrid materials exhibit significant specific capacitance of up to 350 F g -1 , making them promising in large-scale energy-storage device applications. AustraliaAbstract Large scale energy storage system with high power is crucial for addressing the energy problem. The development of high-performance materials is a key issue in realizing grid-scale applications of energy storage devices. In this work, we describe a simple and scalable method to fabricate hybrids (graphene-pyrrole/carbon nanotube-polyaniline (GPCP) using graphene foam as the supporting template. Graphene-pyrrole (G-Py) aerogels are prepared by a green hydrothermal route from 2D materials -graphene sheets, while CNT/PANI composite dispersion is obtained via in-situ polymerization method. The functional nanohybrid materials of GPCP can 2 be assembled together by simply dipping the prepared G-py aerogels into the CNT/PANI dispersion. The morphology of the obtained GPCP are investigated by scanning electron microscopy (SEM) and transmission electron microscope (TEM), which revealed that CNT/PANI were uniformly deposited onto the surfaces of graphene. The as-synthesized GPCP maintains the original three-dimensional (3D) hierarchical porous architecture, which favor the diffusion of the electrolyte ions into the inner region of active materials. Such hybrid materials exhibit significant specific capacitance of up to 350 F g -1 , making them promising in large-scale energy storage device applications.

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Preparation of polyaniline/graphene oxide nanocomposite for the application of supercapacitor

Cited by 158 publications

References 29 publications

Effect of hydrothermal reaction time and alkaline conditions on the electrochemical properties of reduced graphene oxide

Effect of hydrothermal reaction time and alkaline conditions on the electrochemical properties of reduced graphene oxide

Thermally conductive thin films derived from defect free graphene-natural rubber latex nanocomposite: Preparation and properties

Fabrication of graphene foam supported carbon nanotube/polyaniline hybrids for high-performance supercapacitor applications

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