Preparation of Polymer@PbS hybrid nanofibers by surface-initiated atom transfer radical polymerization and acidolysis by H2S

Surface-Initiated Controlled Radical Polymerization: State-of-the-Art, Opportunities, and Challenges in Surface and Interface Engineering with Polymer Brushes

“…Often polymer brush nanoparticle or quantum dot composite films are obtained via reduction of appropriate precursor salts. One strategy to obtain polymer brush films that incorporate metal salts is the polymerization of appropriate metal-containing (methacrylate) monomers. , Specific examples include the SI-ATRP of cadmium and lead dimethacrylate followed by treatment with H 2 S to generate the nanoparticle hybrids.…”

“…Polymer brushes have found varied usage in photonic applications. One approach involves the use of the polymer brush to attach photoluminescent moieties. ,,,,,,, Alternatively, polymer brushes can be grafted directly from photoluminescent nanoparticles. , The later approach has been shown to improve the dispersion and near-band-edge emission of nanoparticles . Further, the intrinsic processability of the grafted polymer allows incorporation of fluorescent moieties into functional materials such as polystyrene-grafted fluorescent carbon nanoparticles being electrospun into a fiber mat .…”

“…One approach involves the use of the polymer b r u s h t o a t t a c h p h o t o l u m i n e s c e n t m o ieties. 645,695,744,801,817,1044,1134,1135 Alternatively, polymer brushes can be grafted directly from photoluminescent nanoparticles. 1136,1137 The later approach has been shown to improve the dispersion and near-band-edge emission of nanoparticles.…”

Transition metal sulfides meet electrospinning: versatile synthesis, distinct properties and prospective applications

“…The gas-solid reaction provides an efficient and versatile route to fabricate uniform and small-sized metal sulfide nanoparticles in electrospun nanofibers. [68][69][70][71] Through a gas-solid reaction upon to the electrospun polymer/metal salt hybrid nanofibers, the obtained metal sulfide nanoparticles are mainly distributed within the polymer nanofibers. To achieve the formation of metal sulfide nanoparticles on the surface of polymer nanofibers, a facile approach is to decorate metal ions on the surface of electrospun nanofibers followed by a post-treatment process.…”