Preparation of porphyrin mono- and multi-layer films based on the polymer Langmuir–Blodgett method

Luminescence Properties of Platinum Porphyrin Embedded in Multilayered Polymer Nanosheets

“…The curve shows steep rise as well as high collapse pressure (> 40 mN/m), indicating that (Figure 3). The molecular orientation of porphyrin moieties at the air-water interface have been reported in previous reports; for example, zinc porphyrin moieties in pADA-Por took faceon orientation [25]; metal-free porphyrin moieties have an out-ofplane orientation in poly(iBMA-co-AOTPP) monolayers [26]. In that sense, PtTPP takes a remarkably vertical orientation because of high compressibility modulus of DDA side chains.…”

Spectroscopic and optical characterization of porphyrin chromophores incorporated into ultrathin polyimide films

“…The optical system of this measurement is shown in Fig. 6 [31]. In this study, three types of the orientations of porphyrin moieties were assumed: random, parallel to the substrate, and perpendicular to the substrate.…”

“…Porphyrins, which play an important role in the photosynthesis of plants, are preferable photosensitizers for utilizing solar energy because of the large absorption bands in the ultraviolet-visible region [26]. So far, many studies have been done on LB films of porphyrins [24,[27][28][29][30][31][32][33][34]. However, aggregation of porphyrins in LB films causes crucial Scheme 1.…”

Synthesis of 5-(4-methacrylamidophenyl)-10,15,20-triphenylporphyrin, its copolymerization with acrylamide and EDMA, use of this copolymer in the adsorption of bovine serum albumin

“…In the literature there are reports for the preparation of porphyrin bearing monomers [25][26][27] as well as porphyrins with suitable groups for the post-polymerization reaction.…”