Preparation of resins having various phosphonium groups and their adsorption and elution behavior for anionic surfactants

Abstract

ABSTRACT:Resins containing phosphonium groups were prepared by reaction of chlorohydroxylated glycidylmethacrylate-divinylbenzene macroreticular resins with three trialkylphosphines. Triethylphosphine, tributylphosphine, and trioctylphosphine were used as trialkylphosphines. Adsorption and elution behavior of sodium benzenesulfonate (SBS) and sodium dodecylbenzenesulfonate (SDBS) on the resins were studied. Adsorption of SBS and SDBS increased with increasing the alkyl chain length of phosphonium groups in the resins. The adsorption of SBS decreased with increasing ionic strength of the solution, while the adsorption of SDBS increased with increasing ionic strength of the solution.

Preparation and thermal studies of self-crosslinked terpolymer derived from 4-acetylpyridine oxime, formaldehyde and acetophenone

“…This study was performed with a sealed aluminum capsule pan, under a nitrogen atmosphere, at four different heating rates (10,20,30, and 40 C/min) between 30 and 250 C. Terpolymers were subjected to TGA in a nitrogen atmosphere at four different heating rates (10,20,30, and 40 C/ min) from 30 to 600 C with a thermogravimetric analyzer (Mettler Toledo AG 2007). For the removal of moisture from the resins, the resins were mounted in a vacuum-dried oven at 30 C for 48 h.…”

“…Counter anions that form a strong ion-pair with the polymer impede the antimicrobial activity because the counter ion will prevent the polymer from interacting with the bacteria. However, ions that form a loose ion-pair or readily dissociate from the polymer, exhibit a positive influence on the activity because it allows the polymer to interact freely with microorganism [30,31]. Cationic terpolymer resins ET-1 (4-HydroxyacetophenoneFormaldehyde-4-Chloroacetophenone) and ET-2 (4-Hydroxyacetophenone-Furfural-4-Chloroacetophenone) which have been previously reported by Chauhan and coworkers [32] are taken for comparative antimicrobial activities with 4-APO-F-A.…”

Mechanism and behavior of surfactant adsorption onto resins with different matrices

“…This promotion is not obvious to the elution of acrylic ester resin because the elution rate is too high to be elevated much more. The observation demonstrates a significant effect of ethanol on the elution, and the results may be related to the interfering effect of ethanol and alkaline on the hydrophobic interaction and electrostatic attraction [13].…”

Preparation of superabsorbent polymer hydrogels from trialkyl-4-vinylbenzyl phosphonium chloride-acrylamide-methylenebisacrylamide terpolymers and their properties

“…We have reported that similar behavior was observed with copolymer beads carrying phosphonium groups. 14 Next, the adsorption ability for SDBS and SBS of terpolymers obtained at 3 mol % of TOVB and 3-10 mol % of MBAAm in feed was measured in deionized water (Fig. 12).…”

“…[7][8][9] On the other hand, Kanazawa et al 10,11 have reported that water-soluble polymers with phosphonium groups had high antibacterial activity against bacteria such as Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). We have also reported the preparation of several waterinsoluble resins [12][13][14] having antibacterial activity to prevent the residual toxicity of water-soluble bactericides in water, as well as on high antibacterial activity against such bacteria and by copolymers beads containing quaternary ammonium, phosphonium, or other cationic groups, such beads having high adsorption ability for anionic surfactants such as sodium dodecyl benzenesulfonate, even from its salt solution. 12,14 For this study we synthesized hydrogels having phosphonium groups by the terpolymerization of tri-4-vinylbenzyl phosphonium chloride (TRVB) with alkyl chains of different lengths, acrylamide (AAm), and N,N'-methylenebisacrylamide (MBAAm).…”