1897
DOI: 10.1021/ja02075a005
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Preparation of Sodium Nitroprusside.

Abstract: HE literature referring to this compound is usually more or less incomplete in regard to the details of its preparation ; but, unless it is prepared in the pure state, its use as a delicate reagent is somewhat impaired, Place sixty grams pulverized potassium ferrocyanide in a medium-sized evaporating dish, and pour on it a solution consisting of 150 grams concentrated nitric acid (sp. gr. 1.42) diluted with 100 cc. of water. Perform the operation under a hood or in a draft of air. When the evolution of gases … Show more

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Cited by 4 publications
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“…673 However, both methods were time consuming and hazardous, as they also yielded chlorine dioxide (ClO 2 ) gas, 104 which can explosively decompose into oxygen and chlorine. 674 Graphite oxide (GrO) flakes were already investigated by Kohlschtter and Haenni in 1918, 675 and the first TEM images reported in 1948 by Ruess and Vogt 676 showed the presence of single sheets of GO.…”
Section: Productionmentioning
confidence: 99%
“…673 However, both methods were time consuming and hazardous, as they also yielded chlorine dioxide (ClO 2 ) gas, 104 which can explosively decompose into oxygen and chlorine. 674 Graphite oxide (GrO) flakes were already investigated by Kohlschtter and Haenni in 1918, 675 and the first TEM images reported in 1948 by Ruess and Vogt 676 showed the presence of single sheets of GO.…”
Section: Productionmentioning
confidence: 99%
“…The Staudenmaier method28 typically produces the most oxidized GO, though the entire synthesis may take several days. Unfortunately, both it and the Brodie method27 generate ClO 2 gas, which must be handled with caution due to its high toxicity and tendency to decompose in air to produce explosions ranging from “the toot of a small whistle to the noise of a firecracker” 32. As such, the Hummers method,29 with its relatively shorter reaction time and absence of hazardous ClO 2 , has seen more use in current research.…”
Section: Graphene Oxide‐based Materialsmentioning
confidence: 99%
“…This allowed carrying out the reaction in a single vessel, streamlining the production process 103 . However, both methods were time consuming and hazardous, as they also yielded chlorine dioxide (ClO 2 ) gas 104 , which can explosively decompose into oxygen and chlorine 104 . Graphite oxide flakes were already investigated by Kohlschtter and Haenni in 1918 105 , and the first TEM images reported in 1948 by Ruess and Vogt 106 showed the presence of single GO sheets.…”
Section: Lpe Of Graphite Oxidementioning
confidence: 99%