Preparation of Some Polymerizable Esters of Oleic Acid with Unsaturated Alcohols

Vapor-Liquid Equilibria for the Methyl Oleate and Methyl Stearate Binary System.

“…4 Liang (5) 152.3 into an olefinic polymerization reaction very slowly even when in a reactive system composed of methallyl oleate and vinyl acetate with 1% of benzoyl peroxide as a catalyst at temperatures above 100°C. (16). It does not seem that the methyl oleate-methyl stearate system in the absence of a catalyst and air would form any polymer during the brief periods of the present experiments.…”

Polymerizable monomers from castor oil. I. Vinyl monomers based on undecenoic acid

“…Allyl esters of the fatty acids were prepared readily by direct esterification with an acid catalyst and azeotropic removal of water with benzene (14). Allyl esters of the fatty acids were prepared readily by direct esterification with an acid catalyst and azeotropic removal of water with benzene (14).…”

“…Altyl Ester. Allyl esters of the fatty acids were prepared readily by direct esterification with an acid catalyst and azeotropic removal of water with benzene (14). Alternatively, refluxing 1 mole of acid with 10 moles of allyl alcohol together with 2% p-toluenesulphonic acid for 6-8 hr' gave excellent yields of allyl esters.…”

Epoxy Esters as Plasticizers and Stabilizers for Vinyl Chloride Polymers

“…Epoxidized Esters of Oleic Acid. The following esters were prepared in the conventional manner by direct esterification of oleic acid with the appropriate alcohol, using naphthalene-2-sulfonic acid as catalyst and benzene or toluene as the entraining agent for separation of water (26). The numbers in parentheses are the boiling point and pressure in millimeters, and iodine number; all distillations were conducted from an alembic flask.…”