Preparation of the first iminodisulfurylazide: A nitrogen bound covalent azide containing an N4 unit

Methylated Derivatives of Hydrazinium Azide

“…The reaction of tetramethylhydrazine with HN 3 is different from the other reactions since a clear solution forms after the addition of HN 3 . After distilling off ether and HN 3 , it was possible to isolate a yellowish oil that was purified by low temperature sublimation. (2) Compounds 3Ϫ6 are all sensitive to oxidation.…”

Azidotris(trifluoromethyl)germane, (CF3)3GeN3: Spectroscopic Characterization and Density Functional Computations

“…Azidotris(trifluoromethyl)germane was fully characterized by multinuclear NMR spectroscopy (Table ). For the covalently bound species, three well-resolved resonances were found in the 14 N NMR spectrum (Figure ) and assignment of the individual resonances to N1, N2, and N3 (connectivity: Ge−N1−N2−N3) was made on the basis of the arguments given in earlier work by Witanowski and three reports on 14 N data of covalent azides by us. , The individual chemical shifts as well as line widths found for 1 nicely compare to those of the structurally closely related As(N 3 ) 3 and also IN 3 (cf. electronegativities, Allred/Rochow: Ge, 2.0; As, 2.2; I, 2.2) (Table ).…”

“…We have been studying the reactions of various nitrogen, phosphorus, arsenic, and antimony halides with silver azide and activated sodium azide. − In 1992/1994 Ang et al published structural studies on the trifluoromethyl-substituted arsenic azides (CF 3 )As(N 3 ) 2 and (CF 3 ) 2 AsN 3 , and there is also a report on the preparation of ionic trimethylazidoarsonium compounds …”

Synthesis, Spectroscopic Investigation, and Theoretical Study of the Ruthenium Diazide Complex [Ru(tpy)(PPh3)(N3)2]

“…14N NMR spectroscopy was also used to char acterize the prepared diazide complex. From earlier l4N NMR data for coordinated azides [12,13], indi vidually well resolved resonances of Na, Nb, and Nc (connectivity: Ru-Na-Nb-Nc) have been assigned in the 14N NMR spectrum of the complex. Each res onance at -337, -136, and -225 ppm corresponds to azide coordinated to Ru in the [Ru(tpy)(PPh3)2-(Nß)]+ complex [6], Although the three N atoms of the tpy ligand system in the [Ru(tpy)(PPh3)2 (^3 )2] complex could not be observed, the three nitrogen chemical shifts for the diazide ligands coordinated to the ruthenium atom in the complex were obtained at -335, -132, -278 ppm.…”