Preparation of Thermosensitive Fluorescent Polyacrylamide Nanofiber Membrane and Visual Temperature Sensing

Abstract

Fluorescent fibers are capable of discoloration behavior under special light sources, showing great potential for applications in biomedicine, environmental monitoring, heavy-metal-ion detaction, and anti-counterfeiting. In the current paper, temperature-sensitive fluorescent poly-acrylamide (PAM) nanofiber (AuNCs@PAM NF) membranes are prepared by mixing red fluorescent gold nanoclusters (AuNCs) synthesized in-house with PAM using the electrospinning technique. The AuNCs@PAM nanofibers obtained using this method present excellent morphology, and the AuNCs are uniformly dispersed in the fibers. The average diameter of the AuNCs@PAM NFs is 298 nm, and the diameter of AuNCs doped in the fibers is approximately 2.1 nm. Furthermore, the AuNCs@PAM NF films present excellent fluorescence and temperature-sensitive performance between 15 and 65 degrees. While under the 365 nm UV light source, the fiber film changes from white to red; this discoloration behavior weakens with the increase in temperature, and changes from deep to light red. Therefore, the approximate temperature can be identified using the color change, and a visual temperature-sensing effect can be achieved. The dual functions of temperature-sensitivity and fluorescent properties improve the scientificity and safety of nanofibers in the use of anti-counterfeiting technology.

Flat ultrafiltration PAN/BNE membranes with temperature-responsive performance obtained by modification with “smart” PVA copolymer

“…The ability for HMPVA to be located in the membrane structure will expand the membrane's performance capabilities related to its permeability and selectivity according to temperature conditions and within the limits critical for stimulating the sensitivity of the "smart" polymer. The choice of the receiving pure (unmodified) membrane and its qualities are of great importance for the result [13][14][15][16][17].…”