1993
DOI: 10.1016/0955-2219(93)90126-c
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Preparation of ThO2/Y2O3 powders by the sol-gel method for solid electrolytes

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Cited by 5 publications
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“…These investigations encouraged us further to determine the extent of dissolution of these rare‐earths in thoria matrix. Also, the amount of rare‐earth ion dissolution in thoria has been reported to depend critically on the method of synthesis in addition to other considerations such as ionic size and preference to form oxygen‐deficient fluorite‐related structure . Xerogels with molar compositions of 50%, 60%, and 70% of Ln 3+ in the series, Th 1− x Ln x O 2−δ (Ln = Yb 3+ , Tm 3+ , Er 3+ , and Ho 3+ ) could be readily obtained.…”
Section: Resultsmentioning
confidence: 99%
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“…These investigations encouraged us further to determine the extent of dissolution of these rare‐earths in thoria matrix. Also, the amount of rare‐earth ion dissolution in thoria has been reported to depend critically on the method of synthesis in addition to other considerations such as ionic size and preference to form oxygen‐deficient fluorite‐related structure . Xerogels with molar compositions of 50%, 60%, and 70% of Ln 3+ in the series, Th 1− x Ln x O 2−δ (Ln = Yb 3+ , Tm 3+ , Er 3+ , and Ho 3+ ) could be readily obtained.…”
Section: Resultsmentioning
confidence: 99%
“…Although singly rare‐earth ion–doped thoria systems have been investigated from the point of view of luminescent materials and for understanding the complex defect chemistry present in them, answers to certain questions have not been reached yet . For example, concentration of LnO 1.5 that could be dissolved in thoria lattice has been found to vary with the mode of synthesis . This has necessitated exploration of alternate methods of synthesis for these systems.…”
Section: Introductionmentioning
confidence: 99%
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