Presence and Origin of Fluoride in the Complex Terminal Water of Ouargla Basin (Northern Sahara of Algeria)

Abstract

<b>Problem statement:</b> The underground waters in the oriental regions of the Algerian Sahara, present real chemical quality problems. Their content in fluorides always exceeds the limit of the recommended levels. That is 0.8 mg L^-1, according to the maximum temperature in the region. Combined to a high salinity, it affects the health of the population living around the region. The present work, deals with the presence of fluoride and the geochemical origin in the Complex Terminal aquifer of Ouargla, rarely examined in the Algerian Sahara. <b>Approach:</b> Is based on the following aspects: Sampling and physico-chemicals analysis of water, statistical treatment of the physico-chemical water parameters and simulation to natural and isotherm 25°C evaporation of water parameters. <b>Results: </b>The results show the presence of fluoride in the studied water. The rates vary between 1 and 2 mg L^-1. The calculation of water saturation index in relation with the preponderant minerals, using the thermodynamic model ‹‹phreeqci›› reveals a sensitivity of carbonate minerals towards precipitation and dissolution of evaporitic minerals and clayey fluorides as well. <b>Conclusions/Recommendations:</b> The increasing alkalinity of water in contact with the aquifer during long periods of stay decreases the chemical activity of calcium and helps with alteration of clayey minerals and fluoride as a necessary condition for a possible fluorite mineralization. Knowing the origin of that fluoridation leads to possible solutions, through the optimization of a water treatment meets the standards

Groundwater physico-chemical properties and water quality changes in shallow aquifers in arid saline wetlands, Ouargla, Algeria

“…Calcite residual alkalinity was therefore negative when sample water solutions were saturated. Alkalinity remained stable, however, with calcium content increase (Gac et al 1979;Ribolzi et al 1993) due to calcium equilibrium with fluoride ion (Barbiero et al 1995;Nezli et al 2009). With gypsum precipitation, calcite + gypsum residual alkalinity was positive, where SO 4 2− + alkalinity > Ca 2+ loads in moles.…”

Fluoride concentrations in groundwater and impact on human health in Siloam Village, Limpopo Province, South Africa

“…Chae et al (2007) reported that the thermodynamic relationship between Ca 2+ and F − ions indicates that fluoride concentration is controlled by equilibrium of fluorite. When the water is saturated with respect to fluorite or is at equilibrium with fluorite, the low calcium concentration leads to higher fluoride concentrations (Nezli et al, 2009). High fluoride concentrations are therefore expected in groundwater from aquifers with low calcium concentrations.…”

Fluoride in Groundwater

“…In each case, the origin of the F was taken to be phosphorite deposits in the sediments. Concentrations in the range 1 to 3 mg/L were found in the Cenozoic Complex Terminal aquifer of Algeria (Kechiched et al, 2020;Nezli et al, 2009). Here, the groundwaters are of Na-HCO 3 and Na-Cl compositions and elevated F concentrations believed influenced by evaporation.…”