Preventing SO_x Emissions through Process Control: Interdigital Capacitors for On-Site Monitoring of Thiophene-Based Environmental Pollutants in Oil Refineries

Abstract

The presence of organosulfur compounds in fossil fuels is a major source of environmental pollution (SOx emissions) and deteriorates the catalytic exhaust systems of automobiles. Therefore, the development of miniaturized, low-cost, robust interdigital capacitors (IDC) is required to precisely monitor organosulfur compounds in petroleum products. Based on the Pearson concept of hard/soft acids/bases (HSAB), NiS nanoparticles were prepared and integrated into chemical, heat, and wear-resistant TiO2 coatings to fabricate sensitive layers on IDC for the detection of benzothiophene (BT) and dibenzothiophene (DBT) in gasoline samples. Compared to NiS nanoparticles and pristine TiO2 sol, TiO2-NiS nanocomposites exhibit distinctive morphology with homogeneous distribution of NiS nanoparticles, high surface roughness, and greater localized nanoscale variations. Therefore, HSAB chemistry and spatially distinctive features of TiO2-NiS/IDC sensors yield excellent response and sensitivity toward BT/DBT. The reproducibility of sensor layers, selectivity, repeatability, and stability of TiO2-NiS/IDC sensor were studied before calibrating the devices for real-time measurements in refined gasoline samples. TiO2-NiS/IDC sensors exhibit a wide-range linear response, high sensitivity, and low detection limits in gasoline. Real-time sensor measurements show a 90.7% recovery of BT/DBT from gasoline samples. The sensors were calibrated in gasoline samples for potential process and quality control applications during crude oil refining.

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“…3f). According to the Randles-Sevc ˇik equation, 34 the plots of I pa and I pc against the square root of scan rate (n 35 Fe/NIPpy nanozymes also demonstrate the diffusioncontrolled electrocatalytic oxidation of spermine (Fig. S5, ESI †).…”

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