2022
DOI: 10.1678/rheology.50.305
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Primitive Chain Network Simulations for Shear Rheology of Poly(propylene carbonate) Melts

Abstract: Although chemistry dependence in the non-linear rheology of polymers has been rather established for uniaxial elongations, it has not been frequently discussed for fast shear. In this study, to see the effect of orientation-dependent monomeric friction on the shear rheology, we conducted primitive chain network simulations for a few poly(propylene carbonate) melts, for which we have determined the friction model from the uniaxial data recently [Yang et al., Nihon Reoroji Gakkaishi, 50, 127-135 (2022)]. The si… Show more

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