Green supply chain management is highly significant to maintain environmental sustainability. The agglomeration of green components enhances and supports the business activities to practice green supply chain more effectively. Utilizing sustainable packaging materials in logistics is a step towards promoting business eco sustainability. This research work attempts to develop a hybrid decision making model by integrating techniques of fuzzy multi criteria decision making (MCDM) and Reinforcement Learning (RL). This research work proposes a decision-making method of IDOCRIW (Integrated Determination of Objective Criteria Weights) under fuzzy environment with linguistic representations to determine the criterion weights of material selection and applies the RL method of Q learning in ranking the packaging materials for promoting green sustainability. The proposed fuzzy based MCDM method resolves the problems of conflict of uncertainty. The ranking results obtained using this method are compared with the non-integrated MCDM method. The proposed combined model shall be discussed under various other extended fuzzy representations. The decision-making problem on optimal selection of packaging materials addressed in this research work benefits the business decision makers to make right choices. This hybrid model will certainly make the logistic environment more robust and also it will upscale the smart framework of supply chain management.