Poor
interfacial quality and low refractive index contrast
(Δn) are critical challenges for the development
of high-performance
one-dimensional photonic crystals (1DPhCs) via solution methods that
impede their optical efficiency. Herein, we introduce an innovative
approach by hybridizing hollow SiO2 with poly(vinyl alcohol),
referred to as PHS, followed by alternate assembly with TiO2 via spin-coating, achieving a 1DPhC with Δn = 0.76 at the wavelength of 550 nm. This method circumvents the
need for high-temperature treatment and complex curing conditions,
resulting in a 1DPhC with superior interfacial and optical characteristics.
By adjusting the thickness of the PHS layers, we can finely tune the
reflectance spectrum, attaining over 99% reflectance at the photonic
band gap. Furthermore, 1DPhC demonstrates excellent adhesion to polycarbonate
substrates and retains its optimal optical performance even after
rigorous environmental testing, including hygrothermal cycles, exposure
to hot water, friction, and solvent sonication. This research paves
the way for the facile fabrication of high-performance 1DPhCs under
mild conditions, offering new perspectives for photonic material processing.