Polypropylene (PP) is a semi‐crystalline polymer that displays simple manufacturing, high stiffness, lightweight, chemical resistance, and inexpensive. However, PP has significant drawbacks, such as poor brittleness at low temperatures, high shrinkage ratio, and low impact resistance, which limit its development. Thermoplastic polyurethane (TPU) possesses recyclable and eco‐friendly characteristics, along with the elasticity of rubber and exceptional mechanical properties. In this study, a flexible and high‐filtration performance PP‐TPU textile material was developed by melt‐blowing for filtering PM0.3 aerosols. For the first time, a melt‐blown PP‐TPU nonwoven was used as an air filter. The fiber morphological studies exhibited that addition of 10 and 20 wt.% TPU into PP resulted in a fiber diameter increment from 0.94 to 1.24 μm. Also, melt‐blown PP‐TPU forms helical fibers, which are different from fibers noticed in melt‐blown PP. Corona‐charged double‐layer 80PP‐20TPU nonwovens have a filtration efficiency of 99.25% and quality factor (QF) of 0.13 mm H2O−1 at an air flow rate of 95 L/min. Moreover, PP's tensile strength was increased by 72.22%, and elongation was raised by 38.1% with the addition of 20 wt.% TPU. Thus, PP‐TPU melt‐blown composites may bring novel perspectives into the design and development of high‐performance filtering materials for a variety of applications.