Phys. Chem. Chem. Phys.
 2023
DOI: 10.1039/d3cp02433d
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Probing molecular interactions of semiquinone radicals at quinone reduction sites of cytochrome bc1 by X-band HYSCORE EPR spectroscopy and quantum mechanical calculations

Patryk Kuleta
1
,
Rafał Pietras
2
,
Justyna Andrys
3
et al.

Abstract: Quinone redox reactions involve semiquinone (SQ) intermediate state. The catalytic sites in enzymes stabilize SQ state by various molecular interactions, such as hydrogen bonding to oxygens of the two carbonyls...

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