To improve traffic efficiency, adaptive traffic signal control (ATSC) systems have been widely developed. However, few studies have proactively optimized the air environmental issues in the development of ATSC. To fill this research gap, this study proposes an optimized ATSC algorithm to take into consideration both traffic efficiency and decarbonization. The proposed algorithm is developed based on the deep reinforcement learning (DRL) framework with dual goals (DRL-DG) for traffic control system optimization. A novel network structure combining Convolutional Neural Networks and Long Short-Term Memory Networks is designed to map the intersection traffic state to a Q-value, accelerating the learning process. The reward mechanism involves a multi-objective optimization function, employing the entropy weight method to balance the weights among dual goals. Based on a representative intersection in Changsha, Hunan Province, China, a simulated intersection scenario is constructed to train and test the proposed algorithm. The result shows that the ATSC system optimized by the proposed DRL-DG results in a reduction of more than 71% in vehicle waiting time and 46% in carbon emissions compared to traditional traffic signal control systems. It converges faster and achieves a balanced dual-objective optimization compared to the prevailing DRL-based ATSC.