Reactive
dividing wall column (RDWC) is a highly integrated configuration
where reaction and separation take place in a single equipment simultaneously.
In this study, three self-heat recuperative reactive dividing wall
column processes are developed to reduce the energy consumption of
RDWC. Latent heat and sensible heat in the processes are recovered
by self-heat recuperation technology. The heat exchanger network using
pinch analysis is applied to optimize the energy utilization. Total
energy consumption, total annual cost, CO2 emissions, and
thermodynamic efficiency are evaluated. Compared with the RDWC, the
results demonstrate that the optimal design of the self-heat recuperative
processes reduces the energy consumption by 58.1% and decreases the
total annual cost by 17.8%. Apart from that, the CO2 emissions
of the optimal design are 87.9% lower than the RDWC and the thermodynamic
efficiency can be increased to 31.4%.