Production of bio-paraffin from solvent-free deoxygenation of palm biodiesel over ZrO2-supported nickel phosphide catalysts

Prasongthum, Natthawan; Suemanotham, Amornrat; Sisuthog, Wanchana; Thanmongkhon, Yoothana; Reubroycharoen, Prasert; Attanatho, Lalita

doi:10.1016/j.apcata.2022.118917

Cited by 9 publications

(3 citation statements)

References 30 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[43] The Ni site with four neighboring P atoms, i. e., Ni(1) site, has a tetrahedral geometry, which is favorable for the decarbonylation reaction; the Ni site with five neighboring P atoms, i. e., Ni(2) site, has a square pyramidal geometry, which is favorable for the hydrogenolysis and hydrogenation steps. [43][44] Attanatho et al [45] prepared a nickel phosphide-supported ZrO 2 catalyst (Ni x P y /ZrO 2 ) to catalyze the preparation of n-paraffin from palm oil and scrutinized the effect of Ni/P molar ratio on the catalytic activity. It was found that Ni 0 , Ni 2 P, Ni 3 P and Ni 12 P 5 phases were formed if the Ni/P molar ratio was greater than 1, while only Ni 2 P was formed if the Ni/P molar ratio was equal to 1.…”

Section: Structural Propertiesmentioning

confidence: 99%

Transition metal phosphides: synthesis nanoarchitectonics, catalytic properties, and biomass conversion applications

Lu,

Yan,

et al. 2024

ChemSusChem

View full text Add to dashboard Cite

Developing inexpensive and efficient catalysts for biomass hydrogenation or hydrodeoxygenation (HDO) is essential for efficient energy conversion. Transition metal phosphides (TMPs), with the merits of abundant active sites, unique physicochemical properties, tunable component structures, and excellent catalytic activities, are recognized as promising biomass hydrogenation or HDO catalytic materials. Nevertheless, the biomass hydrogenation or HDO catalytic applications of TMPs are still limited by various complexities and inherent performance bottlenecks, and thus their future development and utilization remain to be systematically sorted out and further explored. This review summarizes the current popular strategies for the preparation of TMPs. Subsequently, based on the structural and electronic properties of TMPs, the catalytic activity origins of TMPs in biomass hydrogenation or HDO is elucidated. Additionally, the application of TMPs in efficient biomass hydrogenation or HDO catalysis, as well as highly targeted multiscale strategies to enhance the catalytic performance of TMPs, are comprehensively described. Finally, large‐scale amplification synthesis, rational construction of TMP‐based catalysts and in‐depth study of the catalytic mechanism are also mentioned as challenges and future directions in this research field. Expectedly, this review can provide professional and targeted guidance for the rational design and practical application of TMPs biomass hydrogenation or HDO catalysts.

show abstract

Section: Structural Propertiesmentioning

confidence: 99%

Transition metal phosphides: synthesis nanoarchitectonics, catalytic properties, and biomass conversion applications

Lu,

Yan,

et al. 2024

ChemSusChem

View full text Add to dashboard Cite

show abstract

“…Prasongthum et al. [ 289 ] investigated the effect of Ni/P molar ratio on the nickel phosphide supported ZrO 2 for the catalytic conversion of the palm oil to n‐paraffins. It was observed that if Ni/P ratio is 1 only Ni 2 P is formed, if the observed ratio is more than 1 different phases of Ni 0 , Ni 2 P, Ni 12 P 5 , Ni 3 P are formed.…”

Section: Catalytic Potential Of Tmp Toward Versatile Organic Transfor...mentioning

confidence: 99%

“…Additionally, the homogeneous dispersion of NiP on to the TiO 2 provides enhanced active sites for the absorption of H 2 , which in turn accelerates the hydrodeoxygenation reaction. Prasongthum et al [289] investigated the effect of Ni/P molar ratio on the nickel phosphide supported ZrO 2 for the catalytic conversion of the palm oil to n-paraffins. It was observed that if Ni/P ratio is 1 only Ni 2 P is formed, if the observed ratio is more than 1 different phases of Ni 0 , Ni 2 P, Ni 12 P 5 , Ni 3 P are formed.…”

Section: Hydrodeoxygenationmentioning

confidence: 99%

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

Sharma

Choudhary

Kumar

et al. 2023

Small

View full text Add to dashboard Cite

Transition metal phosphides (TMP) posses unique physiochemical, geometrical, and electronic properties, which can be exploited for different catalytic applications, such as photocatalysis, electrocatalysis, organic catalysis, etc. Among others, the use of TMP for organic catalysis is less explored and still facing many complex challenges, which necessitate the development of sustainable catalytic reaction protocols demonstrating high selectivity and yield of the desired molecules of high significance. In this regard, the controlled synthesis of TMP‐based catalysts and thorough investigations of underlying reaction mechanisms can provide deeper insights toward practical achievement of desired applications. This review aims at providing a comprehensive analysis on the recent advancements in the synthetic strategies for the tailored and tunable engineering of structural, geometrical, and electronic properties of TMP. In addition, their unprecedented catalytic potential toward different organic transformation reactions is succinctly summarized and critically analyzed. Finally, a rational perspective on future opportunities and challenges in the emerging field of organic catalysis is provided. On the account of the recent achievements accomplished in organic synthesis using TMP, it is highly anticipated that the use of TMP combined with advanced innovative technologies and methodologies can pave the way toward large scale realization of organic catalysis.

show abstract

Oleic acid decarboxylation to produce C8-C17 alkanes catalyzed by Pt and Ni on a MOF-derived zirconia

Shi,

Wang,

Wang

et al. 2024

J Porous Mater

View full text Add to dashboard Cite

Production of bio-paraffin from solvent-free deoxygenation of palm biodiesel over ZrO2-supported nickel phosphide catalysts

Cited by 9 publications

References 30 publications

Transition metal phosphides: synthesis nanoarchitectonics, catalytic properties, and biomass conversion applications

Transition metal phosphides: synthesis nanoarchitectonics, catalytic properties, and biomass conversion applications

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

Oleic acid decarboxylation to produce C8-C17 alkanes catalyzed by Pt and Ni on a MOF-derived zirconia

Contact Info

Product

Resources

About