Abstract-The suitability of GC-MS simulated distillation as means to determine the boiling range of biodiesel is determined in this study. The study is divided into two sections. Various vegetable oils and animal fats where an acid-and/or alkali-catalyst can be used and diluted with an alcohol to produce biodiesel. The produced biodiesel must meet the SANS 1935:2011 standards where it can be used for diesel engine automobiles [1]. The first section is known as the experimental procedure for the production of biodiesel from various feedstock's and the second section includes the distillation experiment of the biodiesel. The distillation procedure followed the same procedure as specified by the ASTM D86 test method. The test method indicates that the distillation unit must operate at atmospheric pressure but the distillation experiments were conducted at ambient pressure of 86.02 kPa for Potchefstroom. The actual distillation curve and the simulated distillation curve for each biodiesel were compared in order to see if the simulated distillation results predict the same boiling points as the actual distillation. This study has shown that the simulated results obtained from the GC-MS can be used to determine the boiling ranges for biodiesel but it can be better accomplished by using vacuum distillation.